Abstract
Experimental and theoretical study of the Ag- Sn-Te system was carried out in the scope of the study. The isothermal sections at 350 and 500 °C were studied experimentally. The results were used together with other experimental data from the literature for the theoretical assessment of the system by the CALPHAD method. Generally, a very good agreement was obtained both for the phase diagram and for the enthalpies of mixing in the liquid phase. The existence of the ternary phase (AgxSn2-xTe2) was confirmed, and a slightly different composition (x = 0.8) was evaluated in the experimental part of the study.
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B. Cai, H. Hu, H.-L. Zhuang, and J.-F. Li, Promising Materials for Thermoelectric Applications, J. Alloys Compd., 2019, 806, p 471-486.
A. Allouhi, Advances on Solar Thermal Cogeneration Processes Based on Thermoelectric Devices: a Review”, Sol. Energy Mater. Sol. Cells, 2019, 200, p 109954.
G. Tan, M. Ohta, and M.G. Kanatzidis, Thermoelectric Power Generation: From New Materials to Devices, Philos. Trans. R. Soc. A, 2019, 377, p 20180450.
R. Moshwan, L. Yang, J. Zou, and Z.-G. Chen, Eco-Friendly SnTe Thermoelectric Materials: Progress and Future Challenges, Adv. Funct. Mater., 2017, 27, p 1703278.
Y.Z. Pei, N.A. Heinz, and G.J. Snyder, Alloying to Increase the Band Gap for Improving Thermoelectric Properties of Ag2Te, J. Mater. Chem., 2011, 21, p 18256-18260.
C.-H. Su, Design, Growth and Characterization of PbTe-Based Thermoelectric Materials, Prog. Cryst. Growth Charact. Mater., 2019, 65, p 47-94.
L. Zhao, J. Wang, J. Li, J. Liu, C. Wang, J. Wang, and X. Wang, High Thermoelectric Performance of Ag Doped SnTe Polycrystalline Bulks via the Synergistic Manipulation of Electrical and Thermal Transport, Phys. Chem. Chem. Phys., 2019, 21, p 17978-17984.
M.H. Lee, D.-G. Byeon, J.-S. Rhyee, and B. Ryu, Defect Chemistry and Enhancement of Thermoelectric Performance in Ag-Doped Sn1+δ−xAgxTe, J. Mater. Chem. A, 2017, 5, p 2235-2242.
Y. Chen, M.D. Nielsen, Y.-B. Gao, T.- J. Zhu, X. Zhao, and J.P. Heremans, SnTe–AgSbTe2 Thermoelectric Alloys, Adv. Energy Mater., 2012, 2, p 58-62.
J. Wu, J. Yang, H. Zhang, J. Zhang, S. Feng, M. Liu, J. Peng, W. zhu, and T. Zou, Fabrication of Ag-Sn-Sb-Te Based Thermoelectric Materials by MA-PAS and Their Properties, J. Alloys Compd., 2010, 507, p 167-171.
L. Nykyruya, M. Ruvinskiya, E. Ivakinb, O. Kostyuka, I. Horichoka, I. Kisialioub, Y. Yavorskyya, and A. Hrubyaka, Low-Dimensional Systems on the Base of PbSnAgTe (LATT) Compounds for Thermoelectric Application, Phys. E (Amsterdam Neth), 2019, 106, p 10-18.
J. Androulakis, K.-F. Hsu, R. Pcionek, H. Kong, C. Uher, J.J. D’Angelo, A. Downey, T. Hogan, and M.G. Kanatzidis, Nanostructuring and High Thermoelectric Efficiency in p-Type Ag(Pb1–ySny)mSbTe2+m, Adv. Mater., 2006, 18, p 1170-1173.
F.N. Rhines, Phase Diagrams in Metallurgy: Their Development and Application. McGraw-Hill, New York, 1956.
M. Hillert, Phase Equilibria, Phase Diagrams and Phase Transformation: Their Thermodynamic Basis. Cambridge University Press, Cambridge, 1998.
V.B. Rajkumar, and S.-W. Chen, Ag-Se Phase Diagram Calculation Associating ab-Initio Molecular Dynamics Simulation, Calphad, 2018, 63, p 51-60.
R. Blachnik, G. Bolte, and B. Gather, Ternäre Chalkogenhaltige Systeme V Das Ternäre Phasendiagramm Silber-Zinn-Tellur, Z. Metallkde., 1978, 69, p 530-533. , in German
R. Blachnik, and B. Gather, Mischungen Von GeTe, SnTe und PbTe mit Ag2Te. Ein Beitrag zur Klärung der Konstitution der Ternären Ag-IVb-Te systeme (IVb = Ge, Sn, Pb), J. Less-Common Met., 1978, 60, p 25-32. , (in German)
J.S. Chang, S.W. Chen, K.C. Chiu, H.J. Wu, and J.J. Chen, Liquidus Projection of the Ag-Sn-Te Ternary System, Metall. Mater. Trans. A, 2014, 45A, p 3728-3740.
B. Gather, and R. Blachnik, Ag8SnTe6 Ein Neuer Stabiler Vertreter der Argyrodite?, Z. Naturforsch. A Phys. Sci., 1983, 38, p 786-787. , (in German)
B. Gather, and R. Blachnik, Mischungsenthalpien in Ternären Systemen V: Das System Silber-Zinn-Tellur, Z. Met., 1986, 77, p 643-648. , (in German)
F. Römermann, and R. Blachnik, The Excess Enthalpies of Liquid Ag-Ge-Te and Ag-Sn-Te Alloys, Z. Met., 2001, 92, p 336-344.
Y. Liu, D. Liang, and L. Zhang, Thermodynamic Descriptions for the Sn-Te and Pb-Sn-Te Systems, J. Electron. Mater., 2010, 39, p 246-257.
C.-S. Oh, J.-H. Shim, J.-H. Lee, and B.-Y. Lee, A Thermodynamic Study on the Ag-Sb-Sn System, J. Alloys Compd., 1996, 238, p 155-166.
W. Gierlotka, The Thermodynamic Assessment of the Ag-Te System, Private Communication.
N. Saunders, and A.P.P. Miodownik, CALPHAD (Calculation of Phase Diagrams): A Comprehensive Guide. Elsevier Ltd, New York, 1998.
H. Lukas, S.G. Fries, and B. Sundman, Computational Thermodynamics: The Calphad Method. Cambridge University Press, New York, 2007.
J.-O. Andersson, T. Helander, L. Höglund, P. Shi, and B. Sundman, Thermo-Calc & DICTRA, Computational Tools for materials Science, Calphad, 2002, 26, p 273-312.
W. Cao, S.-L. Chen, F. Zhang, K. Wu, Y. Yang, Y.-A. Chang, R. Schmid-Fetzer, and W.A. Oates, PANDAT Software with PanEngine, PanOptimizer and PanPrecipitation for Multicomponent Phase Diagram Calculation and Materials Property Simulation, Calphad, 2009, 33, p 328-342.
A. Dinsdale, SGTE Data for Pure Elements, Calphad, 1991, 15, p 317-425.
SGTE Unary Database, ver. 5.0. www.sgte.net/en/free-pure-substance-database.
O. Redlich, and A.T. Kister, Thermodynamics of Nonelectrolyte Solutions—x-y-t Relations in a Binary System, Ind. Eng. Chem., 1948, 40, p 341-345.
Y.M. Muggianu, M. Gambino, and J.P. Bros, Enthalpies of Formation of Liquid Alloys Bismuth-Gallium-Tin at 723 K–choice of Analytical Representation of Integral and Partial Thermodynamic Functions of Mixing for this Ternary System, J. Chim. Phys., 1975, 72, p 83-88.
A. Dinsdale, A. Kroupa, A. Watson, J. Vrestal, A. Zemanova, and P. Broz, MP0602 HT SOLDERS database, COST MP0602 Action (2012)
R.M. Honea, Empressite and Stuetzite Redefined, Am. Miner., 1964, 49, p 325-338.
A. Watson, Private Report, COST 531 Action, (2008)
H. Flandorfer, C. Luef, and U. Saeed, On the Temperature Dependence of the Enthalpies of Mixing in Liquid Binary (Ag, Cu, Ni)-Sn Alloys, J. Non. Cryst. Solids., 2008, 354, p 2953-2972.
P.Y. Chevalier, Unpublished Work, (2005)
W. Gierlotka, “Thermodynamic Assessment of the Ag–Te Binary System, J. Alloys Compd., 2009, 485, p 231-235.
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The authors acknowledge the financial support of the Ministry of Science and Technology of Taiwan (MOST 107-2923-E-007-005-MY3) and the Czech Science Foundation (Project 18-25660J).
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Chen, Sw., Kroupa, A., Du, Jy. et al. Experimental and Theoretical Study of the Ag-Sn-Te Phase Diagram. J. Phase Equilib. Diffus. 43, 139–163 (2022). https://doi.org/10.1007/s11669-022-00943-y
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DOI: https://doi.org/10.1007/s11669-022-00943-y