Abstract
The phase diagram of the binary Ni-Se system has been modelled by the CALPHAD approach for the first time. The modelled phase diagram is based on a known experimental phase diagram, enthalpy of formation of the NiSe phase and heat capacity of the NiSe2 phase. All calculated data (the Ni-Se phase diagram, the standard enthalpy of mixing of the NiSe phase at 298 K and 1050 K and the heat capacity of NiSe2 in the temperature range 298-1000 K) reveal very good agreement with the experimental results.
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This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors. The raw data required to reproduce these findings are available in appendix.
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Zobač, O., Buchlovská, K., Pavlů, J. et al. Thermodynamic Description of Binary System Nickel-Selenium. J. Phase Equilib. Diffus. 42, 468–478 (2021). https://doi.org/10.1007/s11669-021-00906-9
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DOI: https://doi.org/10.1007/s11669-021-00906-9