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Influence of Thermal Treatment on Microstructure and Corrosion Behavior of Amorphous Fe40Ni40B12Si8 Alloy

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Abstract

Microstructural evolution of thermally treated melt-quenched amorphous Fe40Ni40B12Si8 alloy was studied in terms of its influence on corrosion behavior of the alloy. Alloy structure was transformed gradually from purely amorphous and chemically homogeneous to fully crystalline, yielding γ-(Fe,Ni), Ni31Si12 and (Fe,Ni)2B phases as the final products. Corrosion study of the alloy in amorphous, partially crystalline as well as fully crystalline form, performed by electrochemical measurements in 0.5 M NaCl, together with the morphology examination, revealed that the microstructure and phase composition are crucial factors determining the corrosion resistance of the alloy in corrosive environment.

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Acknowledgments

This research was financially supported by the Ministry of Education, Science and Technological Development of the Republic of Serbia (Contract No. 451-03-68/2020-14/200146) and by the Ministry of Education, Youth and Sports of the Czech Republic under the projects CEITEC 2020 (LQ1601), and m-IPMinfra (CZ.02.1.01/0.0/0.0/16_013/0001823). The authors would like to thank Ing. Pavla Roupcová, PhD (Institute of Physics of Materials AS CR, Brno, Czech Republic) for performing XRD measurements and Dr. Danica Bajuk Bogdanović (Faculty of Physical Chemistry, University of Belgrade, Serbia) for recording Raman spectra.

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  1. Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11000, Belgrade, Serbia

    Milica M. Vasić, Ivana Stojković Simatović & Dragica M. Minić

  2. Institute of Physics of Materials AS CR, Žižkova 22, 616 62, Brno, Czech Republic

    Tomáš Žák & Naděžda Pizúrová

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  1. Milica M. Vasić
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Manuscript submiited May 4, 2020; accepted October 18, 2020.

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Vasić, M.M., Žák, T., Pizúrová, N. et al. Influence of Thermal Treatment on Microstructure and Corrosion Behavior of Amorphous Fe40Ni40B12Si8 Alloy. Metall Mater Trans A 52, 34–45 (2021). https://doi.org/10.1007/s11661-020-06079-3

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