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Licensed Unlicensed Requires Authentication Published by De Gruyter October 29, 2018

Microwave-assisted solvent-free synthesis and spectral and structural characterization of cyclotriphosphazene hexakis(o-tolylamide)

  • Mohammad Hakimi EMAIL logo , Homeyra Rezaei , Keyvan Moeini , Heidar Raissi , Vaclav Eigner and Michal Dušek

Abstract

A new cyclotriphosphazene, 2,2,4,4,6,6-hexakis (o-tolylamono)-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine (MPAP), was prepared using microwave irradiation and identified by elemental analysis, FT-IR, Raman, 31P NMR spectroscopy, and single-crystal X-ray diffraction. In the crystal, in addition to hydrogen bonds, the network is further stabilized by inter- and intramolecular π–π stacking interactions between aromatic rings.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2018-0136).


Received: 2018-06-29
Accepted: 2018-10-02
Published Online: 2018-10-29
Published in Print: 2018-12-19

©2018 Walter de Gruyter GmbH, Berlin/Boston

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