Short-range and long-range correlations in driven dense colloidal mixtures in narrow pores

František Slanina, Miroslav Kotrla, and Karel Netočný
Phys. Rev. E 106, 014610 – Published 25 July 2022

Abstract

The system of a driven dense colloid mixture in a tube with diameter comparable to particle size is modeled by a generalization of the asymmetric simple exclusion process (ASEP) model. The generalization goes in two directions: relaxing the exclusion constraint by allowing several (but few) particles on a site and by considering two species of particles, which differ in size and transport coefficients. We calculate the nearest-neighbor correlations using a variant of the Kirkwood approximation and show by comparison with numerical simulations that the approximation provides quite accurate results. However, for long-range correlations, we show that the Kirkwood approximation is useless, as it predicts exponential decay of the density-density correlation function with distance, while simulation data indicate that the decay is algebraic. For the one-component system, we show that the decay is governed by a power law with universal exponent close to 2. In the two-component system, the correlation function behaves in a more complicated manner: Its sign oscillates but the envelope decays again very slowly and the decay is compatible with a power law with an exponent somewhat lower than 2. Therefore, our generalization of the ASEP belongs to a different universality class from the ensemble of generalized ASEP models which are mappable to zero-range processes.

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  • Received 7 April 2022
  • Accepted 5 July 2022

DOI:https://doi.org/10.1103/PhysRevE.106.014610

©2022 American Physical Society

Physics Subject Headings (PhySH)

Statistical Physics & ThermodynamicsPolymers & Soft Matter

Authors & Affiliations

František Slanina*, Miroslav Kotrla, and Karel Netočný

  • Institute of Physics, Czech Academy of Sciences, Na Slovance 2, 18221 Praha, Czech Republic

  • *slanina@fzu.cz

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Issue

Vol. 106, Iss. 1 — July 2022

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