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Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study

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Abstract

In this work, we report the synthesis, characterization, crystal structure, and thermal and antibacterial studies of a new nano-sized copper(I) thiosemicarbazone complex prepared by an ultrasonic bath assisted synthesis in an acetonitrile solution. Characterization of the complex and its ligand (EHB-tsc = 3-ethoxy-4-hydroxybenzaldehyde-thiosemicarbazone) was performed using elemental analysis, FT-IR, 1H and 13C-NMR, UV–Vis spectroscopy, thermal gravimetry, and single-crystal X-ray diffraction. In addition, the complex was characterized by X-ray powder diffraction and scanning electron microscopy.

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References

  1. P. Mourya, S. Banerjee, R.B. Rastogi, M.M. Singh, Ind. Eng. Chem. Res. 52, 12733–12747 (2013)

    Article  CAS  Google Scholar 

  2. Y.-J. Zhu, K.-K. Song, Z.-C. Li, Z.-Z. Pan, Y.-J. Guo, J.-J. Zhou, Q. Wang, B. Liu, Q.-X. Chen, J. Agric. Food Chem. 57, 5518–5523 (2009)

    Article  CAS  PubMed  Google Scholar 

  3. T.S. Lobana, R. Sharma, G. Bawa, S. Khanna, Coordi. Chem. Rev. 253, 977–1055 (2009)

    Article  CAS  Google Scholar 

  4. T.P. Stanojkovic, D. Kovala-Demertzi, A. Primikyri, I. Garcia-Santos, A. Castineiras, Z. Juranic, M.A. Demertzis, J. Inorg. Biochem. 104, 467–476 (2010)

    Article  CAS  PubMed  Google Scholar 

  5. S.C. Vandana, Spectrochim. Acta A 129, 333–338 (2014)

    Article  CAS  Google Scholar 

  6. K. Alomar, A. Landreau, M. Kempf, M.A. Khan, M. Allain, G. Bouet, J. Inorg. Biochem. 104, 397–404 (2010)

    Article  CAS  PubMed  Google Scholar 

  7. N. Raman, A. Selvan, P. Manisankar, Spectrochim. Acta A 46, 161–173 (2010)

    Article  CAS  Google Scholar 

  8. T.S. Lobana, P. Kumari, R.J. Butcher, Inorg. Chem. Commun. 11, 11–14 (2008)

    Article  CAS  Google Scholar 

  9. T.S. Lobana, R.J. Butcher, Trans. Met. Chem. 29, 291–295 (2004)

    Article  CAS  Google Scholar 

  10. T.S. Lobana, S. Khanna, A. Castineiras, G. Hundal, Z. Anorg. Allg. Chem. 636, 454–456 (2010)

    Article  CAS  Google Scholar 

  11. T.S. Lobana, R. Sharma, G. Hundal, A. Castineiras, R.J. Butcher, Polyhedron 47, 134–142 (2012)

    Article  CAS  Google Scholar 

  12. T.S. Lobana, S. Khanna, R.J. Butcher, A.D. Hunter, M. Zeller, Inorg. Chem. 46, 5826–5828 (2007)

    Article  CAS  PubMed  Google Scholar 

  13. T.S. Lobana, R.J. Butcher, A. Castineiras, E. Bermejo, P.V. Bharatam, Inorg. Chem. 45, 1535–1542 (2006)

    Article  CAS  PubMed  Google Scholar 

  14. M. Hakimi, H. Vahedi, M. Rezvaninezhad, F. Mohr, J. Sulf. Chem. 32, 55–61 (2011)

    Article  CAS  Google Scholar 

  15. E. Shahsavani, N. Feizi, V. Eigner, M. Dusek, A.D. Khalaji, J. Struct. Chem. 56, 1003–1007 (2015)

    Article  CAS  Google Scholar 

  16. A.D. Khalaji, E. Shahsavani, N. Feizi, M. Kucerakova, M. Dusek, R. Mazandarani, A. Amiri, C.R. Chimie 20, 125–131 (2017)

    Article  CAS  Google Scholar 

  17. T.S. Lobana, A. Castineiras, Polyhedron 21, 1603–1603xxxx (2002)

    Article  CAS  Google Scholar 

  18. L. Palatinus, G. Chapuis, J. Appl. Crystallogr. 40, 786–790 (2007)

    Article  CAS  Google Scholar 

  19. V. Petricek, M. Dusek, L. Palatinus, Z. Kristallogr. 229, 345–352 (2014)

    CAS  Google Scholar 

  20. K. Brandenburg, H. Putz. Diamonde crystal and molecular structure visualization. Bonn: Crystal Impact GbR

  21. N.M. Samus, Y.M. Chumakov, V.I. Tsapkov, G. Bocelli, Y.A. Simonov, A.P. Gulya, Russ. J. Gen. Chem. 79, 428–434 (2009)

    Article  CAS  Google Scholar 

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Acknowledgements

We are grateful to the Payame Noor University and Golestan University for the financial support of this work. Structure analysis was supported by the project 18-10504S of the Czech Science Foundation using instruments of the ASTRA lab established within the Operation program Prague Competitiveness e project CZ.2.16/3.1.00/2451.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Golestan University, Gorgān, Iran

    Aliakbar Dehno Khalaji

  2. Department of Chemistry, Payame Noor University, Mashhad, Iran

    Ensieh Shahsavani

  3. Institute of Physic of the Czech Academy of Sciences, Na Slovance 2, 182 21, Prague, Czech Republic

    Michal Dusek & Monika Kucerakova

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  1. Aliakbar Dehno Khalaji
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  2. Ensieh Shahsavani
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Correspondence to Aliakbar Dehno Khalaji.

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Khalaji, A.D., Shahsavani, E., Dusek, M. et al. Sonochemical synthesis and characterization of nano-sized copper(I) thiosemicarbazone complex: crystal structure and thermal study. J IRAN CHEM SOC 16, 1179–1187 (2019). https://doi.org/10.1007/s13738-019-01592-8

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  • DOI: https://doi.org/10.1007/s13738-019-01592-8

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