Abstract
, , and electron paramagnetic resonance and and nuclear magnetic resonance (NMR) measurements are carried out in single crystals at temperatures from 300 K down to 20 K. It was found that the tetragonal crystal-field parameter of the and impurity ions undergoes an unexpected change in its temperature dependence at K: it increases with decreasing temperature to 150–170 K and then strongly decreases with further temperature lowering. Electric-field gradient at Ti site measured from NMR shows nonuniform change with decreasing temperature: it sharply increases with decreasing temperature to 150–170 K and is practically temperature independent below these temperatures. Moreover, substantial broadening of NMR linewidth is seen for Ti and Pb nuclei at K due to essential increase of lattice parameters fluctuations. All these facts may indicate proximity of a transition to another phase with barely perceptible crystal-structure modification as reported in the paper by Kobayashi et al. [Phys. Rev. B 28, 3866 (1983)] while, actually, it was not detected in NMR. The experimental data are compared with those obtained from ab initio calculations.
2 More- Received 22 December 2022
- Revised 6 March 2023
- Accepted 16 March 2023
DOI:https://doi.org/10.1103/PhysRevB.107.104107
©2023 American Physical Society