Abstract
Multimodal contamination-free composite silicon/gold nanoparticles are synthesized by “green” laser ablation approach. Their concentration-dependent size distribution and chemical composition are studied by means of transmission electron microscopy coupled with energy-dispersive X-ray spectroscopy. The influence of applied laser fluence on both size distribution and chemical composition is also investigated. The size-dependent chemical composition of formed nanocomposites is analyzed. Optoelectronic properties of silicon/gold nanoparticles as well as their ability to molecule detection using surface-enhanced Raman scattering are studied as well.
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Amendola V, Scaramuzza S, Litti L, Meneghetti M, Zuccolotto G, Rosato A, Nicolato E, Marzola P, Fracasso G, Anselmi C, Pinto M, Colombatti M (2014) Magneto-Plasmonic au-Fe alloy nanoparticles designed for multimodal SERS-MRI-CT imaging. Small 10:2476–2486. https://doi.org/10.1002/smll.201303372
Anker JN, Hall WP, Lyandres O, Shah NC, Zhao J, van Duyne RP (2008) Biosensing with plasmon nanosensors. Nat Mater 7:442–453. https://doi.org/10.1142/9789814287005_0032
Anthony RJ, Cheng KY, Holman ZC, Holmes RJ, Kortshagen UR (2012) An all-gas-phase approach for the fabrication of silicon nanocrystal light-emitting devices. Nano Lett 12(6):2822–2825. https://doi.org/10.1021/nl300164z
Arce RD, Koropecki RR, Olmos G, Gennaro AM, Schmidt JA (2006) Photoinduced phenomena in nanostructured porous silicon. Thin Solid Films 510:169–174. https://doi.org/10.1016/j.tsf.2005.08.376
Bapat A, Anderson C, Perrey CR, Carter CB, Campbell SA, Kortshagen U (2004) Plasma synthesis of single-crystal silicon nanoparticles for novel electronic device applications. Plasma Phys Controlled Fusion 46:B97–B109. https://doi.org/10.1088/0741-3335
Baran M, Bulakh B, Korsunska N, Khomenkova L, Jedrzejewski J (2004) Luminescence and EPR studies of defects in Si-SiO2 films. Eur Phys J Appl Phys 27:285–287. https://doi.org/10.1051/epjap:2004089
Censabella M, Torrisic V, Boninelli S, Bongiorno C, Grimaldi MG, Ruffino F (2019) Laser ablation synthesis of mono- and bimetallic Pt and Pd nanoparticles and fabrication of Pt-Pd/graphene nanocomposites. Appl Surf Sci 475:494–503. https://doi.org/10.1016/j.apsusc.2019.01.029
Chen Y, Wu H, Li Z, Wang P, Yang L, Fang Y (2012) The study of surface plasmon in Au/Ag core/shell compound nanoparticles. Plasmonics 7:509–513. https://doi.org/10.1007/s11468-012-9336-6
Cui L, Chen P, Yuan Z, Yu C, Ren B, Zhang K (2013) In situ study of the antibacterial activity and mechanism of action of silver nanoparticles by surface-enhanced Raman spectroscopy. Anal Chem 85(11):5436–5443. https://doi.org/10.1021/ac400245j
Detappe A, Thomas E, Tibbitt MW, Kunjachan S, Zavidij O, Parnandi N, Reznichenko E, Lux F, Tillement O, Berbeco R (2017) Ultrasmall silica-based bismuth gadolinium nanoparticles for dual magnetic resonance−computed tomography image guided radiation therapy. Nano Lett 17:1733–1740. https://doi.org/10.1021/acs.nanolett.6b05055
Dolgaev SI, Simakin AV, Voronov VV, Shafeev GA, Bozon-Verduraz F (2002) Nanoparticles produced by laser ablation of solids in liquid environment. Appl Surf Sci 186:546–551. https://doi.org/10.1016/S0169-4332(01)00634-1
Dreaden EC, Alkilany AM, Huang X, Murphy CJ, El-Sayed MA (2012) The golden age: gold nanoparticles for biomedicine. Chem Soc Rev 41:2740–2779. https://doi.org/10.1039/C1CS15237H
El-Zahry MR, Mahmoud A, Refaat IH, Mohamed HA, Bohlmann H, Lendl B (2015) Antibacterial effect of various shapes of silver nanoparticles monitored by SERS. Talanta 138:183–189. https://doi.org/10.1016/j.talanta.2015.02.022
Erogbogbo F, Yong KT, Roy I, Hu R, Law WC, Zhao W, Ding H, Wu F, Kumar R, Swihart MT, Prasad PN (2011) In vivo targeted cancer imaging, sentinel lymph node mapping and multi-channel imaging with biocompatible silicon nanocrystals. ACS Nano 5(1):413–423. https://doi.org/10.1021/nn1018945
Ferrando R, Jellinek J, Johnston RL (2008) Nanoalloys: from theory to applications of alloy clusters and nanoparticles. Chem Rev 108(3):847–910. https://doi.org/10.1021/cr040090g
Gao Z, Ma T, Zhao E, Docter D, Yang W, Stauber RH, Gao M (2016) Small is smarter: nano MRI contrast agents – advantages and recent achievements. Small 12:556–576. https://doi.org/10.1002/smll.201502309
Ge M, Rong J, Fang X, Zhang A, Lu Y, Zhou C (2013) Scalable preparation of porous silicon nanoparticles and their application for lithium-ion battery anodes. Nano Res 6(3):174–181. https://doi.org/10.1007/s12274-013-0293-y
Glazkova EA, Bakina OV, Lerner MI, Pervikov AV (2018) Synthesis and applications of bimetallic nanoparticles of immiscible elements. Recent Pat Nanotechnol 12:132–142. https://doi.org/10.2174/1872210512666180104114850
Han H, Fanga Y, Li Z, Xu H (2008) Tunable surface plasma resonance frequency in ag core/au shell nanoparticles system prepared by laser ablation. Appl Phys Lett 92:023116. https://doi.org/10.1063/1.2829588
He YQ, Liu SP, Kong L, Liu ZF (2005) A study on the sizes and concentrations of gold nanoparticles by spectra of absorption, resonance Rayleigh scattering and resonance non-linear scattering. Spectrochim Acta Part A 61:2861–2866. https://doi.org/10.1016/j.saa.2004.10.035
Hsiao SM, Peng BY, Tseng YS, Liu HT, Chen CH, Lin HM (2017) Preparation and characterization of multifunctional mesoporous silica nanoparticles for dual magnetic resonance and fluorescence imaging in targeted cancer therapy. Microporous Mesoporous Mater 250:210–220. https://doi.org/10.1016/j.micromeso.2017.04.050
Hu L, Chen G (2007) Analysis of optical absorption in silicon nanowire arrays for photovoltaic applications. Nano Lett 7(11):3249–3252. https://doi.org/10.1021/nl071018b
Huang J, Guo M, Ke H, Zong C, Ren B, Liu G, Shen H, Ma Y, Wang X, Zhang H, Deng Z, Chen H, Zhang Z (2015) Rational design and synthesis of γFe2O3 @Au magnetic gold nanoflowers for efficient cancer theranostics. Adv Mater 27:5049–5056. https://doi.org/10.1002/adma.201501942
Jung HJ, Lee SJ, Koutavarapu R, Kim SK, Choi HC, Choi MY (2018) Enhanced catalytic dechlorination of 1,2-dichlorobenzene using Ni/Pd bimetallic nanoparticles prepared by a pulsed laser ablation in liquid. Catalysts 8:390. https://doi.org/10.3390/catal8090390
Kelzenberg MD, Turner-Evans DB, Kayes BM, Filler MA, Putnam MC, Lewis NS, Atwater HA (2008) Photovoltaic measurements in single-nanowire silicon solar cells. Nano Lett 8(2):710–714. https://doi.org/10.1021/nl072622p
Kim J, Kim HS, Lee N, Kim T, Kim H, Yu T, Song IC, Moon WK, Hyeon T (2008) Multifunctional uniform nanoparticles composed of a magnetite nanocrystal core and a mesoporous silica shell for magnetic resonance and fluorescence imaging and for drug delivery. Angew Chem Int Ed 47:8438–8441. https://doi.org/10.1002/ange.200802469
Konstantinova EA, Ryabchikov YV, Osminkina LA, Vorontsov AS, Kashkarov PK (2004) Effect of adsorption of the donor and acceptor molecules at the surface of porous silicon on the recombination properties of silicon nanocrystals. Semiconductors 38(11):1344–1349. https://doi.org/10.1134/1.1823072
Konstantinova EA, Demin VA, Vorontzov AS, Ryabchikov YV, Belogorokhov IA, Osminkina LA, Forsh PA, Kashkarov PK, Timoshenko VY (2006) Electron paramagnetic resonance and photoluminescence study of Si nanocrystals – photosensitizers of singlet oxygen molecules. J Non-Cryst Solids 352:1156–1159. https://doi.org/10.1016/j.jnoncrysol.2005.12.017
Kutrovskaya S, Arakelian S, Kucherik A, Osipov A, Evlyukhin A, Kavokin AV (2017) The synthesis of hybrid gold-silicon nano particles in a liquid. Sci Rep 7:10284. https://doi.org/10.1038/s41598-017-09634-y
Lasemi N, Miguel OB, Lahoz R, Lennikov VV, Pacher U, Rentenberger C, Kautek W (2018) Laser-assisted synthesis of colloidal FeWxOy and Fe/FexOy nanoparticles in water and ethanol. ChemPhysChem 19:1414–1419. https://doi.org/10.1002/cphc.201701214
Lee JE, Lee N, Kim H, Kim J, Choi SH, Kim JH, Kim T, Song IC, Park SP, Moon WK, Hyeon T (2010) Uniform mesoporous dye-doped silica nanoparticles decorated with multiple magnetite nanocrystals for simultaneous enhanced magnetic resonance imaging, fluorescence imaging, and drug delivery. J Am Chem Soc 132:552–557. https://doi.org/10.1021/ja905793q
Link S, Mohamed MB, El-Sayed MA (1999) Simulation of the optical absorption spectra of gold nanorods as a function of their aspect ratio and the effect of the medium dielectric constant. J Phys Chem B 103:3073–3077. https://doi.org/10.1021/jp990183f
Makarov SV, Petrov MI, Zywietz U, Milichko V, Zuev D, Lopanitsyna N, Kuksin A, Mukhin I, Zograf G, Ubyivovk E, Smirnova DA, Starikov S, Chichkov BN, Kivshar YS (2017) Efficient second-harmonic generation in nanocrystalline silicon nanoparticles. Nano Lett 17(5):3047–3053. https://doi.org/10.1021/acs.nanolett.7b00392
Rao SV, Podagatlapalli GK, Hamad S (2014) Ultrafast laser ablation in liquids for nanomaterials and applications. J Nanosci Nanotechnol 14:1364–1388. https://doi.org/10.1166/jnn.2014.9138
Ryabchikov YV (2019) Size modification of optically active contamination-free silicon nanoparticles with paramagnetic defects by their fast synthesis and dissolution. Phys Status Solidi A 216:1800685. https://doi.org/10.1002/pssa.201800685
Ryabchikov YV, Belogorokhov IA, Vorontsov AS, Osminkina LA, Timoshenko VY, Kashkarov PK (2007) Dependence of the singlet oxygen photosensitization efficiency on morphology of porous silicon. Phys Status Solidi A 204(5):1271–1275. https://doi.org/10.1002/pssa.200674306
Ryabchikov YV, Belogorokhov IA, Gongalskiy MB, Osminkina LA, Timoshenko VY (2011) Photosensitized generation of singlet oxygen in powders and aqueous suspensions of silicon nanocrystals. Semiconductors 45(8):1059–1063. https://doi.org/10.1134/S106378261108015X
Ryabchikov YV, Alekseev SA, Lysenko V, Bremond G, Bluet JM (2013a) Photoluminescence thermometry with alkyl-terminated silicon nanoparticles dispersed in low-polar liquids. Phys Stat Solidi RRL 7(6):414–417. https://doi.org/10.1002/pssr.201307093
Ryabchikov YV, Alekseev SA, Lysenko V, Bremond G, Bluet JM (2013b) Photoluminescence of silicon nanoparticles chemically modified by alkyl groups and dispersed in low-polar liquids. J Nanopart Res 15(4):1535. https://doi.org/10.1007/s11051-013-1535-3
Ryabchikov YV, Lysenko V, Nychyporuk T (2014) Enhanced thermal sensitivity of silicon nanoparticles embedded in (nano-Ag)/SiNx for luminescent thermometry. J Phys Chem C 118:12515–12519. https://doi.org/10.1021/jp411887s
Ryabchikov YV, Popov AA, Sentis M, Timoshenko VY, Kabashin AV (2016) Structural properties of gold-silicon nanohybrids formed by femtosecond laser ablation in water at different fluences. Proc SPIE 9737:97370F-1-6. https://doi.org/10.1117/12.2217777
Ryabchikov YV, Al-Kattan A, Chirvony V, Sanchez-Royo JF, Sentis M, Timoshenko VY, Kabashin AV (2017) Influence of oxidation state on water solubility of Si nanoparticles prepared by laser ablation in water. Proc SPIE 10078:100780C. https://doi.org/10.1117/12.2257404
Saha K, Agasti SS, Kim C, Li X, Rotello VM (2012) Gold nanoparticles in chemical and biological sensing. Chem Rev 112(5):2739–2779. https://doi.org/10.1021/cr2001178
Shcherbakov MR, Neshev DN, Hopkins B, Shorokhov AS, Staude I, Melik-Gaykazyan EV, Decker M, Ezhov AA, Miroshnichenko AE, Brener I, Fedyanin AA, Kivshar YS (2014) Enhanced third-harmonic generation in silicon nanoparticles driven by magnetic response. Nano Lett 14(11):6488–6492. https://doi.org/10.1021/nl503029j
Soenen SJ, Parak WJ, Rejman J, Manshian B (2015) (Intra)cellular stability of inorganic nanoparticles: effects on cytotoxicity, particle functionality, and biomedical applications. Chem Rev 115:2109–2135. https://doi.org/10.1021/cr400714j
Srinoi P, Chen YT, Vittur V, Marquez MD, Lee TR (2018) Bimetallic nanoparticles: enhanced magnetic and optical properties for emerging biological applications. Appl Sci 8:1106. https://doi.org/10.3390/app8071106
Su X, Wu Q, Li J, Xiao X, Lott A, Lu W, Sheldon BW, Wu J (2014) Silicon-based nanomaterials for lithium-ion batteries: a review. Adv Eng Mater 4:1300882. https://doi.org/10.1002/aenm.201300882
Sundaravel B, Sekar K, Kuri G, Satyam PV, Dev BN, Bera S, Narasimhan SV, Chakraborty P, Caccavale F (1999) XPS and SIMS analysis of gold silicide grown on a bromine passivated Si(111) substrate. Appl Surf Sci 137:103–112. https://doi.org/10.1016/S0169-4332(98)00378-X
Tan D, Zhou S, Qiu J, Khusro N (2013) Preparation of functional nanomaterials with femtosecond laser ablation in solution. J Photochem Photobiol C 17:50–68. https://doi.org/10.1016/j.jphotochemrev.2013.08.002
Tao Y, Ju E, Ren J, Qu X (2015) Bifunctionalized mesoporous silica-supported gold nanoparticles: intrinsic oxidase and peroxidase catalytic activities for antibacterial applications. Adv Mater 27:1097–1104. https://doi.org/10.1002/adma.201405105
Tasciotti E, Liu X, Bhavane R, Plant K, Leonard AD, Price BK, Cheng MMC, Decuzzi P, Tour JM, Robertson F, Ferrari M (2008) Mesoporous silicon particles as a multistage delivery system for imaging and therapeutic applications. Nat Nanotechnol 3:151–157. https://doi.org/10.1038/nnano.2008.34
Thakor AS, Gambhir SS (2013) Nanooncology: the future of cancer diagnosis and therapy. CA Cancer J Clin 63:395–418. https://doi.org/10.3322/caac.21199
Timoshenko VY, Kudryavtsev AA, Osminkina LA, Vorontsov AS, Ryabchikov YV, Belogorohov IA, Kovalev D, Kashkarov PK (2006) Silicon nanocrystals as photosensitizers of active oxygen for biomedical applications. JETP Lett 83(9):423–426. https://doi.org/10.1134/S0021364006090128
Verma S, Rao BT, Sathe V, Bhartiya S, Patel HS, Kaul R, Singh B (2018) Optical and surface enhanced Raman scattering responses of densely packed Ag-Au alloy nanoparticle films of varied composition and thickness. J Alloys Compd 753:395–406. https://doi.org/10.1016/j.jallcom.2018.04.216
Wang H, Jiang X, Lee ST, He Y (2014) Silicon nanohybrid-based surface-enhanced Raman scattering sensors. Small 10(22):4455–4468. https://doi.org/10.1002/smll.201401563
Wang G, Gao W, Zhang X, Mei X (2016) Au nanocage functionalized with ultra-small Fe3O4 nanoparticles for targeting T1–T2 dual MRI and CT imaging of tumor. Sci Rep 6:28258. https://doi.org/10.1038/srep28258
Wu H, Yu G, Pan L, Liu N, McDowell MT, Bao Z, Cui Y (2013) Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles. Nat Commun 4:1943. https://doi.org/10.1038/ncomms2941
Zeng H, Du XW, Singh SC, Kulinich SA, Yang S, He J, Cai W (2012) Nanomaterials via laser ablation/irradiation in liquid: a review. Adv Funct Mater 22:1333–1353. https://doi.org/10.1002/adfm.201102295
Zhang L, Gu FX, Chan JM, Wang AZ, Langer RS, Farokhzad OC (2008) Nanoparticles in medicine: therapeutic applications and developments. Clin Pharmacol Ther 83(5):761–769. https://doi.org/10.1038/sj.clpt.6100400
Zhang B, Gökce S, Barcikowski S (2017) Laser synthesis and processing of colloids: fundamentals and applications. Chem Rev 117:3990–4103. https://doi.org/10.1021/acs.chemrev.6b00468
Zhao Y, Li S, Zeng Y, Jiang Y (2015) Synthesis and properties of Ag/ZnO core/shell nanostructures prepared by excimer laser ablation in liquid. APL Mater 3:086103. https://doi.org/10.1063/1.4928287
Zhu XY, Wang AJ, Chen SS, Luo X, Feng JJ (2018) Facile synthesis of AgPt@Ag core-shell nanoparticles as highly active surface-enhanced Raman scattering substrates. Sensors Actuators B Chem 260:945–952. https://doi.org/10.1016/j.snb.2017.12.185
Acknowledgments
This research work was financially supported from the Excellence Initiative of the German Research Foundation of Free University, Berlin (0503121810), from the European Regional Development Fund and the state budget of the Czech Republic (Project BIATRI: CZ.02.1.01/0.0/0.0/15_003/0000445), from the Ministry of Education, Youth and Sports (Programs NPU I-Project no. LO1602) and from the COST project (ECOST-STSM-BM1205-120416-072252). The author also thanks Prof. J. Behrends for performing experiments; Prof. M. Štěpánek and A. Murmiliuk for kind assistance with DLS and Z-potential measurements; and Dr. Al. Popov, Dr. M. Kögler, Dr. S. Uusitalo, and Dr. A. Kabashin for helpful discussions.
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Ryabchikov, Y.V. Facile laser synthesis of multimodal composite silicon/gold nanoparticles with variable chemical composition. J Nanopart Res 21, 85 (2019). https://doi.org/10.1007/s11051-019-4523-4
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DOI: https://doi.org/10.1007/s11051-019-4523-4