Počet záznamů: 1
Pervaporation of (R)/(S)-Methyl 3-Hydroxybutyrate (∑MHB) from a Mixture Containing an Ionic Liquid, Methanol and Ru Catalyst.
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SYSNO ASEP 0503819 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Pervaporation of (R)/(S)-Methyl 3-Hydroxybutyrate (∑MHB) from a Mixture Containing an Ionic Liquid, Methanol and Ru Catalyst. Tvůrce(i) Gaálová, Jana (UCHP-M) RID, SAI, ORCID
Hejda, Stanislav (UCHP-M) RID, ORCID, SAI
Stavárek, Petr (UCHP-M) RID, ORCID, SAI
Sýkora, Jan (UCHP-M) RID, ORCID, SAI
Fajgar, Radek (UCHP-M) RID, ORCID, SAI
Klusoň, Petr (UCHP-M) RID, ORCID, SAI
Izák, Pavel (UCHP-M) RID, ORCID, SAIZdroj.dok. Separation and Purification Technology. - : Elsevier - ISSN 1383-5866
Roč. 222, SEP 1 (2019), s. 45-52Poč.str. 8 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova methyl 3 - hydroxybutyrate ; pervaporation ; ionic liquid Vědní obor RIV CI - Průmyslová chemie a chemické inženýrství Obor OECD Chemical process engineering CEP GA17-00089S GA ČR - Grantová agentura ČR Způsob publikování Omezený přístup Institucionální podpora UCHP-M - RVO:67985858 UT WOS 000468714100006 EID SCOPUS 85064075206 DOI 10.1016/j.seppur.2019.04.017 Anotace Complex technologies in the production of fine chemicals bring together various connected processes, each bringing specific green chemistry challenges. A valuable mixture arises in the stereoselective hydrogenation of methyl-acetoacetate (MAA) to (R)- and (S)- methyl 3-hydroxybutyrate (∑MHB) over Ru organometallic complex (R)-Ru/BINAP, and in a green tetra-alkylammonium bistriflimide/methanol/water solvent phase. The reaction could be carried out in various arrangements, e.g. in a batch mode, in a continuous stirred-tank reactor, or even in a tubular microfluidic chip reactor. In either case, the valuable optically pure Ru complex has been sought to be effectively separated, and potentially recycled. The ionic liquid phase (tetra-alkylammonium bistriflimide) is intended for selective accommodation of the complex in the reaction mixture and as a green alternative to other solvents. It was the main issue of this work to design a specific separation unit, to construct it, and to optimize its performance towards the efficient separation of ∑MHB from the ionic liquid phase bearing the (R)-Ru/BINAP complex. The unit was developed to be connected with the complex preparation process, employing the microreactor fluid flow platform. The separation part of the overall technology was designed as a membrane pervaporation. The membrane separation proceeded with different feed mixtures combining ∑methyl 3-hydroxybutyrate, methanol, ionic liquid and/or the catalyst. The technique was applied at various temperatures, using the industrial composite PDMS membrane, PERVAP™ 4060 from Sulzer. The feed as well as the pervaporate were analyzed by nuclear magnetic resonance spectroscopy and infrared spectroscopy. The enrichment factor of the ∑MHB with respect to the retentate was 1.24 and the ∑MHB permeate mass flux was 61 g h −1 m −2 . In addition, the membrane was characterized by scanning electron microscopy and energy dispersive X-ray microanalysis after the membrane process, showing no sorption of the catalyst into the membrane. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2020 Elektronická adresa http://hdl.handle.net/11104/0295889
Počet záznamů: 1