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Platinum-group elements and gold in base metal sulfides, platinum-group minerals, and Re-Os isotope compositions of the Uitkomst complex, South Africa
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SYSNO ASEP 0488682 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Platinum-group elements and gold in base metal sulfides, platinum-group minerals, and Re-Os isotope compositions of the Uitkomst complex, South Africa Tvůrce(i) Trubač, Jakub (GLU-S) ORCID, RID, SAI
Ackerman, Lukáš (GLU-S) RID, SAI, ORCID
Gauert, Ch. (ZA)
Ďurišová, Jana (GLU-S) RID, SAI
Hrstka, Tomáš (GLU-S) RID, SAIZdroj.dok. Economic Geology. - : Society of Economic Geologists - ISSN 0361-0128
Roč. 113, č. 2 (2018), s. 439-461Poč.str. 23 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova binary alloys ; copper compounds ; economic geology ; gold ; iridium ; isotopes ; ore deposits ; osmium ; palladium ; platinum ; platinum metals ; pyrites ; Rhenium ; rhenium alloys ; ruthenium ; solid solutions ; sulfur compounds ; crustal materials ; mass-balance calculations ; massive sulfides ; mineralized zone ; monosulfide solid solutions ; platinum group elements ; platinum group elements (PGEs) ; platinum group minerals Vědní obor RIV DB - Geologie a mineralogie Obor OECD Geology CEP GA13-15390S GA ČR - Grantová agentura ČR Institucionální podpora GLU-S - RVO:67985831 UT WOS 000429317200006 EID SCOPUS 85043366492 DOI 10.5382/econgeo.2018.4557 Anotace The Uitkomst Complex is a Ni-Cu-PGE-Cr-Co mineralized composite mafic-ultramafic intrusion situated in South Africa. The platinum-group elements (PGEs), Re and Au contents in base metal sulfides (BMS), and Re-Os isotope compositions were determined, as well as the occurrence of associated platinum-group minerals (PGMs) in the various mineralized zones of the complex. BMS within the complex have elevated PGE and Au contents, with the highest values (average of ~10 ppm total PGE) for the massive sulfide body, much lower than the values for BMS from the nearby Bushveld Complex. Pentlandite, as major PGE carrier, hosts most of the Pd, whereas pyrrhotite is characterized by elevated iridium subgroup platinum-group element (IPGE - Os, Ir, Ru) content lacking Pd. Chalcopyrite occasionally serves as a carrier of Au. Minor pyrite concentrates Rh and Re. Mass balance calculations show that BMS play a crucial role in IPGE deportment, whereas they accommodate only up to ~60% of the total Pd. The initial :187Os/188Os values for the whole Uitkomst suite indicate a significant but variable contribution of crustal material to mantle-derived parental melts. Platinum-group elements forming inclusions or presented in solid solution within BMS appear to contribute less to the overall PGE grade than the associated PGMs. The data support the model of a sulfide-oversaturated Uitkomst magma forming a monosulfide solid solution (mss) cumulate as massive sulfide orebody under low-R factor conditions in a shallow conduit after escape of an evolved PGE-rich sulfide liquid from the chamber, leaving the mss relatively poor in PGEs. Pracoviště Geologický ústav Kontakt Jana Popelková, popelkova@gli.cas.cz, Sabina Janíčková, Tel.: 233 087 272 Rok sběru 2019
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