Počet záznamů: 1

Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure

SYSNO ASEP	0436124
Druh ASEP	J - Článek v odborném periodiku
Zařazení RIV	J - Článek v odborném periodiku
Poddruh J	Článek ve WOS
Název	Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure
Tvůrce(i)	Montazerozohori, M. (IR) Musavi, S.A. (IR) Masoudiasl, A. (IR) Naghiha, A. (IR) Dušek, Michal (FZU-D)_{RID, ORCID, SAI} Kučeráková, Monika (FZU-D)_{RID, ORCID}
Zdroj.dok.	Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. - : Elsevier - ISSN 1386-1425 Roč. 137, FEB (2015), s. 389-396
Poč.str.	8 s.
Jazyk dok.	eng - angličtina
Země vyd.	NL - Nizozemsko
Klíč. slova	Schiff base ; Cd(II) ; DNA cleavage ; TG/DTG analysis ; X-ray structure analysis
Vědní obor RIV	BM - Fyzika pevných látek a magnetismus
CEP	GA14-03276S GA ČR - Grantová agentura ČR
Institucionální podpora	FZU-D - RVO:68378271
UT WOS	000347269900054
EID SCOPUS	84907157740
DOI	10.1016/j.saa.2014.08.070
Anotace	Two new cadmium(II) complexes with the formula CdL2(NCS)2 and CdL2(N3)2 (L = 2,2-dimethyl-N,N0 -bis-(3-phenyl-allylidene)-propane-1,3-diamine) have been synthesized and characterized by elemental analysis, molar conductivity measurements, FT/IR, UV-Visible, 1H and 13C NMR spectra and X-ray studies. Two Schiff base ligands are bonded to cadmium(II) ion as N2-donor chelate. Coordination geometry around the cadmium is a octahedron. The C-H…π and C-H…S nteractions give rise a supramolecular structure. The cadmium complexes were screened in vitro for their antibacterial and antifungal activities. Moreover, the compounds were subjected for DNA-cleavage potential by gel electrophoresis method. Finally thermo-gravimetric analysis of the complexes was applied for thermal behavior studies and basic thermo-kinetics activation parameters were evaluated.
Pracoviště	Fyzikální ústav
Kontakt	Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579
Rok sběru	2015

Počet záznamů: 1