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Phase equilibria with hydrate formation in H2O + CO2 mixtures modeled with reference equations of state
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SYSNO ASEP 0386688 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Phase equilibria with hydrate formation in H2O + CO2 mixtures modeled with reference equations of state Tvůrce(i) Jäger, A. (DE)
Vinš, Václav (UT-L) RID, ORCID
Gernert, J. (DE)
Span, R. (DE)
Hrubý, Jan (UT-L) RID, ORCIDZdroj.dok. Fluid Phase Equilibria. - : Elsevier - ISSN 0378-3812
Roč. 338, Januar (2013), s. 100-113Poč.str. 14 s. Forma vydání Tištěná - P Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova carbon dioxide ; gas hydrate ; modeling Vědní obor RIV BJ - Termodynamika CEP GPP101/11/P046 GA ČR - Grantová agentura ČR GAP101/11/1593 GA ČR - Grantová agentura ČR Institucionální podpora UT-L - RVO:61388998 UT WOS 000314737000012 DOI 10.1016/j.fluid.2012.10.017 Anotace Formation of gas hydrates is an important feature of the water–carbon dioxide system. An accurate description of thermodynamic properties of this system requires a consistent description of both fluid and solid states and of their respective phase equilibria. In this study, we modified and refitted the gas hydrate model by A.L. Ballard and E.D. Sloan to combine it with highly accurate equations of state (EoS) in form of the Helmholtz energy and Gibbs energy for other phases formed in the water–carbon dioxide system, e.g., IAPWS-95 and IAPWS formulation for water ice Ih. Since the gas hydrate model uses the fugacity of the gas component in the coexisting phase as an input variable, the accuracy of the predicted phase equilibria was significantly improved by using highly accurate EoSs for coexisting phases. The new hydrate model can be used in a temperature range of 150–295 K and at pressures up to 500 MPa. Pracoviště Ústav termomechaniky Kontakt Marie Kajprová, kajprova@it.cas.cz, Tel.: 266 053 154 ; Jana Lahovská, jaja@it.cas.cz, Tel.: 266 053 823 Rok sběru 2014
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