Počet záznamů: 1
Metastable states in NO2+ probed with Auger spectroscopy
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SYSNO ASEP 0368117 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Metastable states in NO2+ probed with Auger spectroscopy Tvůrce(i) Püttner, R. (DE)
Sekushin, V. (DE)
Fukuzawa, H. (JP)
Uhlíková, T. (CZ)
Špirko, Vladimír (UOCHB-X) ORCID
Asahina, T. (JP)
Kuze, N. (JP)
Kato, H. (JP)
Hoshino, M. (JP)
Tanaka, H. (JP)
Thomas, T. D. (US)
Kukk, E. (FI)
Tamenori, Y. (JP)
Kaindl, G. (DE)
Ueda, K. (JP)Celkový počet autorů 15 Zdroj.dok. Physical Chemistry Chemical Physics. - : Royal Society of Chemistry - ISSN 1463-9076
Roč. 13, č. 41 (2011), s. 18436-18446Poč.str. 11 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova NO2+metastable states ; Auger spectroscopy ; vibrational energies Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEZ AV0Z40550506 - UOCHB-X (2005-2011) UT WOS 000295731100022 DOI 10.1039/c1cp21584a Anotace High-resolution N 1s and O 1s photoelectron spectra (PES) of NO are presented together with spectra of the subsequent Auger decay. The PES are analyzed by taking spin-orbit splitting of the 2P ground state into account providing detailed information on equilibrium distances, vibrational energies, and lifetime widths of the core-ionized states. In the Auger electron spectra (AES) transitions to five metastable dicationic final states are observed, with two of them previously unobserved. A Franck–Condon analysis of the vibrational progressions belonging to these transitions provides detailed information on the potential-energy curves of the dicationic final states as well as on the relative Auger rates. The present calculations of the potential-energy curves of NO2+ agree well with the experimental results and allow an assignment of the two hitherto unresolved Auger transitions to excited states of NO2+, C2S+ and c4P. Pracoviště Ústav organické chemie a biochemie Kontakt asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434 Rok sběru 2012
Počet záznamů: 1