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Semi-Empirical Model of Toluene Transport in Polyethylene Membranes Based on the Data Using a New Type of Apparatus for Determining Gas Permeability, Diffusivity and Solubility
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SYSNO ASEP 0364388 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Semi-Empirical Model of Toluene Transport in Polyethylene Membranes Based on the Data Using a New Type of Apparatus for Determining Gas Permeability, Diffusivity and Solubility Tvůrce(i) Setničková, Kateřina (UCHP-M) RID, ORCID, SAI
Wagner, Zdeněk (UCHP-M) RID, SAI, ORCID
Noble, R. (FR)
Uchytil, Petr (UCHP-M) RID, SAIZdroj.dok. Chemical Engineering Science. - : Elsevier - ISSN 0009-2509
Roč. 66, č. 22 (2011), s. 5566-5574Poč.str. 9 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova mass transfer ; diffusion ; membranes Vědní obor RIV CB - Analytická chemie, separace CEP GA104/09/1165 GA ČR - Grantová agentura ČR ME 889 GA MŠMT - Ministerstvo školství, mládeže a tělovýchovy GCP106/10/J038 GA ČR - Grantová agentura ČR CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000295724600012 DOI 10.1016/j.ces.2011.07.037 Anotace Solubility, diffusivity and permeability of toluene vapors in low-density polyethylene (LDPE) membranes of various thicknesses at different temperatures 30, 40 and 50 degrees C in the range of relative vapor pressure were measured using new type of permeation apparatus. Moreover, special construction of the new cell enables determination of the permeant amount sorbed in the membrane in the steady state operation of vapor permeation. The simple semi-empirical model of toluene transport in a polyethylene membrane based on relation between experimentally obtained effective diffusion coefficients and concentration dependent diffusion coefficients evaluated from experiments on a new permeation apparatus was proposed. The model enables estimation of toluene fluxes, sorption in the steady state of vapor permeation and concentration profiles in a polyethylene membrane from equilibrium sorption isotherms and effective diffusion coefficients. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2012
Počet záznamů: 1