Počet záznamů: 1
H-1-, C-13-, and N-15-NMR chemical shifts for selected glucosides and ribosides of aromatic cytokinins
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SYSNO ASEP 0359282 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název H-1-, C-13-, and N-15-NMR chemical shifts for selected glucosides and ribosides of aromatic cytokinins Tvůrce(i) Vícha, J. (CZ)
Maloň, Michal (UEB-Q)
Veselá, P. (CZ)
Humpa, O. (CZ)
Strnad, Miroslav (UEB-Q) RID, ORCID
Marek, R. (CZ)Zdroj.dok. Magnetic Resonance in Chemistry. - : Wiley - ISSN 0749-1581
Roč. 48, č. 4 (2010), s. 318-322Poč.str. 5 s. Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova NMR ; H-1 ; C-13 Vědní obor RIV EB - Genetika a molekulární biologie CEP GA301/08/1649 GA ČR - Grantová agentura ČR CEZ AV0Z50380511 - UEB-Q (2005-2011) UT WOS 000276337700008 DOI https://doi.org/10.1002/mrc.2575 Anotace The H-1 and C-13 NMR resonances of 16 purine glucosides were assigned by a combination of one- and two-dimensional NMR experiments, including gs-COSY, gs-HSQC, and gs-HMBC, in order to characterize the effect of substituent and the position of glucose unit on the NMR chemical shifts. In addition, N-15 NMR chemical shifts for selected derivatives were investigated by using H-1-N-15 chemical shift correlation techniques. To map the influence of sugar moiety on the directly bonded nitrogen atom, selected N-9-glucosides and their ribose analogs were compared. Characteristic long-range H-1-N-15 coupling constants, measured by using H-1-N-15 gradient-selected single-quantum multiple bond correlation (GSQMBC), are also reported and discussed. All compounds investigated here belong to cytokinins, an important group of plant hormones. Pracoviště Ústav experimentální botaniky Kontakt David Klier, knihovna@ueb.cas.cz, Tel.: 220 390 469 Rok sběru 2011
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