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Voltammetric determination of the herbicide Bifenox in drinking and river water using a silver solid amalgam electrode
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SYSNO ASEP 0358328 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Voltammetric determination of the herbicide Bifenox in drinking and river water using a silver solid amalgam electrode Tvůrce(i) Barek, J. (CZ)
Cabalková, D. (CZ)
Fischer, J. (CZ)
Navrátil, Tomáš (UFCH-W) RID, ORCID
Pecková, K. (CZ)
Josypčuk, Bohdan (UFCH-W) RID, SAI, ORCIDZdroj.dok. Environmental Chemistry Letters - ISSN 1610-3653
Roč. 9, č. 1 (2011), s. 83-86Poč.str. 4 s. Jazyk dok. eng - angličtina Země vyd. DE - Německo Klíč. slova differential pulse voltammetry ; silver solid amalgam electrode ; solid phase extraction Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEP GA203/07/1195 GA ČR - Grantová agentura ČR CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000287708200014 DOI 10.1007/s10311-009-0250-x Anotace A new method for the determination of submicromolar and nanomolar concentrations of herbicide Bifenox using differential pulse voltammetry at a mercury meniscus modified silver solid amalgam electrode is described. This new type of working electrode is non-toxic, environmentally friendly, and compatible with principles of green analytical chemistry, and its surface can be easily electrochemically renewed in the case of passivation. The newly developed direct differential pulse voltammetric determination of Bifenox gives limit of determination 6.7 center dot 10(-7) and 6.9 center dot 10(-7) M in drinking and river water, respectively. Both the selectivity and the sensitivity can be further increased by preliminary separation and preconcentration using solid phase extraction. This combination enables to reach limit of determination 0.9 x 10(-9) and 1.5 x 10(-9) M for drinking and river water, respectively. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2012
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