Počet záznamů: 1
Threshold Photoelectron Spectroscopy of the Methyl Radical Isotopomers, CH3, CH2D, CHD2 and CD3: Synergy between VUV Synchrotron Radiation Experiments and Explicitly Correlated Coupled Cluster Calculations
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SYSNO ASEP 0356830 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Threshold Photoelectron Spectroscopy of the Methyl Radical Isotopomers, CH3, CH2D, CHD2 and CD3: Synergy between VUV Synchrotron Radiation Experiments and Explicitly Correlated Coupled Cluster Calculations Tvůrce(i) Cunha de Miranda, B. K. (FR)
Alcaraz, Ch. (FR)
Elhanine, M. (FR)
Noller, B. (DE)
Hemberger, P. (DE)
Fischer, I. (DE)
Garcia, G. A. (FR)
Soldi-Lose, H. (FR)
Gans, B. (FR)
Mendes, L. A. V. (FR)
Boyé-Péronne, S. (FR)
Douin, S. (FR)
Žabka, Ján (UFCH-W) RID, ORCID, SAI
Botschwina, P. (DE)Zdroj.dok. Journal of Physical Chemistry A. - : American Chemical Society - ISSN 1089-5639
Roč. 114, č. 14 (2010), s. 4818-4830Poč.str. 13 s. Jazyk dok. eng - angličtina Země vyd. US - Spojené státy americké Klíč. slova Threshold photoelectron spectroscopy ; isotopomers ; clusters Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEZ AV0Z40400503 - UFCH-W (2005-2011) UT WOS 000276341300018 DOI 10.1021/jp909422q Anotace Threshold photoelectron spectra (TPES) of the isotopomers of the methyl radical (CH3, CH2D, CHD2, and CD3) have been recorded in the 9.5-10.5 eV VUV photon energy range using third generation synchrotron radiation to investigate the vibrational spectroscopy of the corresponding cations at a 7-11 meV resolution. A threshold photoelectron-photoion coincidence (TPEPICO) spectrometer based on velocity map imaging and Wiley-McLaren time-of-flight has been used to simultaneously record the TPES of several radical species produced in a Ar-seeded beam by dc flash-pyrolysis of nitromethane (CHxDyNO2, x + y = 3). Vibrational bands belonging to the symmetric stretching and out-of-plane bending modes have been observed and P, Q, and R branches have been identified in the analysis of the rotational profiles. Pracoviště Ústav fyzikální chemie J.Heyrovského Kontakt Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Rok sběru 2011
Počet záznamů: 1