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A Relationship between Pore Shapes and Mercury Porosimetry Curves as Revealed by a Random Pore Networks
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SYSNO ASEP 0356434 Druh ASEP C - Konferenční příspěvek (mezinárodní konf.) Zařazení RIV D - Článek ve sborníku Název A Relationship between Pore Shapes and Mercury Porosimetry Curves as Revealed by a Random Pore Networks Tvůrce(i) Čapek, P. (CZ)
Hejtmánek, Vladimír (UCHP-M) RID, SAIZdroj.dok. Characterisation of Porous Solids VIII. - Cambridge : Royal Society of Chemistry Publishing, 2009 / Kaskel S. ; Llewellyn P. ; Rodriguez-Reinoso F. ; Seaton N.A. - ISSN 0260-6291 - ISBN 978-1-84755-904-3 Rozsah stran s. 385-393 Poč.str. 9 s. Akce International Symposium on the Characterization of Porous Solids /8./ Datum konání 10.06.2008-13.06.2008 Místo konání Edinburg Země GB - Velká Británie Typ akce WRD Jazyk dok. eng - angličtina Země vyd. GB - Velká Británie Klíč. slova pore network model ; mercury porosimetry ; external pressure Vědní obor RIV CF - Fyzikální chemie a teoretická chemie CEP GA203/05/0347 GA ČR - Grantová agentura ČR CEZ AV0Z40720504 - UCHP-M (2005-2011) UT WOS 000269656900051 Anotace We developed a random pore network model that was a geometrical simplification of a macroporous medium. The network consisted of chambers interconnected by pore throats and had the same total porosity and external size as pellets of the real medium. Chamber volume and throat size distributions and network connectedness were derived from replicas of the porous medium. The replicas were obtained by means of three-dimensional stochastic reconstruction. Free network parameters involved chamber shape throat shape,and levels of spatial correlation between chamber and throat sizes and between adjacent chamber sizes. Then, we developed a simulator of mercury intrusion and withdrawal, which could handle the formation of mercury menisci in chambers and throats of our particular geometry. The simulator of mercury intrusion was based on the mechanism of invasion percolation. Pracoviště Ústav chemických procesů Kontakt Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Rok sběru 2011
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