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Novel nonlinear optical materials based on dihydropyridine organic chromophore deposited on mica substrate
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SYSNO ASEP 0342928 Druh ASEP J - Článek v odborném periodiku Zařazení RIV J - Článek v odborném periodiku Poddruh J Článek ve WOS Název Novel nonlinear optical materials based on dihydropyridine organic chromophore deposited on mica substrate Tvůrce(i) Kolev, T. (BG)
Koleva, B. (BG)
Kasperczyk, J. (PL)
Kityk, I. (PL)
Tkaczyk, S. (PL)
Spiteler, M. (DE)
Reshak, Ali H (UEK-B)
Kuznik, W. (PL)Celkový počet autorů 8 Zdroj.dok. Journal of Materials Science-Materials in Electronics. - : Springer - ISSN 0957-4522
Roč. 20, č. 11 (2009), s. 1073-1077Poč.str. 5 s. Jazyk dok. eng - angličtina Země vyd. NL - Nizozemsko Klíč. slova nanoncrystallites Vědní obor RIV BO - Biofyzika CEZ AV0Z60870520 - UEK-B (2005-2011) UT WOS 000269913500004 DOI 10.1007/s10854-008-9828-5 Anotace We have synthesized novel composites based on a 1-methyl-4-[2-(3-methoxy-4-oxocyclohexadienyliden)ethyliden]-1,4-dihydropyridine chromophore incorporated into a polymer PMMA host (weight content of 7.5%) deposited on the mica substrate. In the result of simultaneous application of external dc-electric field and thermal heating we have measured values of second order optical effect of about 122 pm/V at 1,064 nm fundamental laser wavelength. This effect show very weak reversibility after the dc-field switching off. Optical properties of the embedded compound were elucidated by means of IR-LD spectroscopy of oriented colloids in nematic host. UV-spectroscopy, 1H- and 13C-NMR methods were also used. Quantum chemical calculations have been carried out in order to describe electronic structure and optical properties. Pracoviště Ústav výzkumu globální změny Kontakt Nikola Šviková, svikova.n@czechglobe.cz, Tel.: 511 192 268 Rok sběru 2011
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