Photochemical Derivatization of Helicenes.

0497000 - ÚCHP 2019 CZ eng C - Konferenční příspěvek (zahraniční konf.)
Jakubec, Martin - Ghosh, I. - Storch, Jan - König, B.
Photochemical Derivatization of Helicenes.
Book of Abstracts. Louvain-la-Neuve: Université catholique de Louvain, 2018 - (Gaigneux, E.), s. 85, č. článku P 21. ISBN N.
[Advances in Organic, Bioorganic and Pharmaceutical Chemistry LIBLICE 2018 /53./. Lázně Bělohrad (CZ), 02.11.2018-04.11.2018]
Grant CEP: GA MPO FV10082
Institucionální podpora: RVO:67985858
Klíčová slova: helicene * photochemistry * substrates
Obor OECD: Organic chemistry

This work is focused on the use of simple helicene derivatives as substrates for modern photochemical methods. Halogen containing substrates are transformed in the reductive pathway to helicenyl radicals, before being trapped by different radical traps. In the oxidative pathway, activated alkoxyhelicenes undergo photoredox catalyzed reactions, yielding various carbon-carbon, as well as carbon-heteroatom containing compounds.

Trvalý link: http://hdl.handle.net/11104/0289612