Electrochemical Hydrogen Oxidation in Toluene/LiCB11Me12: H2 as a Surrogate for Lithium Metal?

0468867 - ÚFCH JH 2017 RIV DE eng J - Článek v odborném periodiku
Pospíšil, Lubomír - Kaleta, Jiří - Michl, Josef
Electrochemical Hydrogen Oxidation in Toluene/LiCB11Me12: H2 as a Surrogate for Lithium Metal?
ChemElectroChem. Roč. 3, č. 2 (2016), s. 332-336. ISSN 2196-0216. E-ISSN 2196-0216
Grant CEP: GA ČR GA13-19213S
Institucionální podpora: RVO:61388955 ; RVO:61388963
Klíčová slova: electrochemistry * hydrogen * lithium
Kód oboru RIV: CG - Elektrochemie; CF - Fyzikální chemie a teoretická chemie (UOCHB-X)
Impakt faktor: 4.136, rok: 2016

In toluene containing LiCB11(CH3)(12) as the supporting electrolyte, the oxidation potential of H-2 on a platinized Pt electrode is a strong function of the composition of a basic buffer, lithium 2,2,6,6-tetramethylpiperidinate / 2,2,6,6-tetramethylpiperidine, and can approach the onset of the reduction of Li+. This suggests that only a moderate voltage might be needed to use H-2 as a surrogate for Li and to take advantage of the specific chemical reactivity of the latter.
Trvalý link: http://hdl.handle.net/11104/0266689