The carbonization of granular polyaniline to produce nitrogen-containing carbon

0360012 - ÚMCH 2012 RIV CH eng J - Článek v odborném periodiku
Rozlívková, Zuzana - Trchová, Miroslava - Exnerová, Milena - Stejskal, Jaroslav
The carbonization of granular polyaniline to produce nitrogen-containing carbon.
Synthetic Metals. Roč. 161, 11/12 (2011), s. 1122-1129. ISSN 0379-6779. E-ISSN 0379-6779
Grant CEP: GA AV ČR IAA100500902; GA AV ČR IAA400500905; GA ČR GA203/08/0686
Výzkumný záměr: CEZ:AV0Z40500505
Klíčová slova: polyaniline * conducting polymer * carbon
Kód oboru RIV: CD - Makromolekulární chemie
Impakt faktor: 1.829, rok: 2011

Polyaniline (PANI) was prepared by the oxidative polymerization of aniline. The deprotonated product, a PANI base, was carbonized in an inert atmosphere at temperatures up to 800 °C for various times. The mass decreased to 40–50 wt.% at temperatures above 600 °C. The progress of molecular structure during carbonization was followed by infrared and Raman spectroscopies. The carbonization at 650 °C for 1 h is suggested for the optimum conversion of PANI to carbon. The product retained the original globular structure of PANI. The conductivity of the carbonized material was low for carbonizations below 600 °C, <10−10 S cm−1, and increased to 10−4 S cm−1 after treatment at 800 °C. The content of nitrogen, not, vert, similar10 wt.%, was not affected appreciably by the carbonization.
Trvalý link: http://hdl.handle.net/11104/0006468