Structure-property Relationships and the Impact of Impurities on the Physico-chemical Properties for Novel Oligoglyme-substituted Ionic Liquids.

0496734 - ÚCHP 2019 CH eng C - Konferenční příspěvek (zahraniční konf.)
Rotrekl, Jan - Bendová, Magdalena - Wagner, Zdeněk - Storch, Jan - Aim, Karel - Sýkora, Jan - Hovorka, Š. - Vrbka, P.
Structure-property Relationships and the Impact of Impurities on the Physico-chemical Properties for Novel Oligoglyme-substituted Ionic Liquids.
Book of Abstracts. 2016, č. článku OC12. ISBN N.
[International Symposium on Solubility Phenomena and Related Equilibrium Processes /17./. Geneva (CH), 24.07.2016-29.07.2016]
Grant CEP: GA MŠMT LD14090
Institucionální podpora: RVO:67985858
Klíčová slova: relationships * ionic liguids * impurities
Obor OECD: Physical chemistry

Ionic liquids (ILs) represent a group of organic salts with an enormous variability in chemical structure and physico-chemical properties and consequently with a broad application potential. The aim of this work is to establish relationships between the chemical structure and physico-chemical properties of the studied Ils and to identify the influence of coloured impurities on these properties.
In a previous study addressing the physico-chemical properties of 1-butyl-3-alkyl-imidazolium bistriflate, where alkyl is a pentyl, isopentyl, or cyclopentyl, a strong influence of the isomerization of the studied ILs was found, allowing for a fine-tuning of their properties. In the present work, the butyl substituent was replaced by
2-(2-ethoxyethoxy)ethyl. The introduction of an (oligo)ether group was choosen with regard to a possible electrochemical application, as this substituent can significantly improve the IL conductivity.
Trvalý link: http://hdl.handle.net/11104/0289385