Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure

0436124 - FZÚ 2015 RIV NL eng J - Článek v odborném periodiku
Montazerozohori, M. - Musavi, S.A. - Masoudiasl, A. - Naghiha, A. - Dušek, Michal - Kučeráková, Monika
Synthesis, spectral, crystal structure, thermal behavior, antimicrobial and DNA cleavage potential of two octahedral cadmium complexes: A supramolecular structure.
Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy. Roč. 137, FEB (2015), s. 389-396. ISSN 1386-1425. E-ISSN 1873-3557
Grant CEP: GA ČR(CZ) GA14-03276S
Institucionální podpora: RVO:68378271
Klíčová slova: Schiff base * Cd(II) * DNA cleavage * TG/DTG analysis * X-ray structure analysis
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 2.653, rok: 2015

Two new cadmium(II) complexes with the formula CdL2(NCS)2 and CdL2(N3)2 (L = 2,2-dimethyl-N,N0 -bis-(3-phenyl-allylidene)-propane-1,3-diamine) have been synthesized and characterized by elemental analysis, molar conductivity measurements, FT/IR, UV-Visible, 1H and 13C NMR spectra and X-ray studies. Two Schiff base ligands are bonded to cadmium(II) ion as N2-donor chelate. Coordination geometry around the cadmium is a octahedron. The C-H…π and C-H…S nteractions give rise a supramolecular structure. The cadmium complexes were screened in vitro for their antibacterial and antifungal activities. Moreover, the compounds were subjected for DNA-cleavage potential by gel electrophoresis method. Finally thermo-gravimetric analysis of the complexes was applied for thermal behavior studies and basic thermo-kinetics activation parameters were evaluated.
Trvalý link: http://hdl.handle.net/11104/0239900