Počet záznamů: 1
Theoretical study on the complexation of the cesium cation with dibenzo-18-crown-6
- 1.0359586 - ÚMCH 2012 RIV AT eng J - Článek v odborném periodiku
Toman, Petr - Makrlík, E. - Vaňura, P.
Theoretical study on the complexation of the cesium cation with dibenzo-18-crown-6.
Monatshefte fur Chemie. Roč. 142, č. 6 (2011), s. 569-571. ISSN 0026-9247. E-ISSN 1434-4475
Grant CEP: GA ČR(CZ) GAP205/10/2280
Výzkumný záměr: CEZ:AV0Z40500505
Klíčová slova: crown ethers * macrocycles * complexation
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.532, rok: 2011
By using quantum mechanical calculations, the most probable structures of free dibenzo-18-crown-6 ligand and the cationic complex species of Cs+ both with one and with two dibenzo-18-crown-6 ligands were derived. In these two complexes, the ‘‘central’’ cation Cs+ is bound by strong bond interactions to the corresponding ethereal oxygen atoms of the parent crown ligand.
Trvalý link: http://hdl.handle.net/11104/0006444
Počet záznamů: 1