Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces

0348914 - ÚFCH JH 2011 RIV DE eng J - Článek v odborném periodiku
Partovi-Nia, R. - Su, B. - Méndez, M. A. - Habermeyer, B. - Gros, C. P. - Barbe, J.-M. - Samec, Zdeněk - Girault, H. H.
Dioxygen Reduction by Cobalt(II) Octaethylporphyrin at Liquid vertical bar Liquid Interfaces.
ChemPhysChem. Roč. 11, č. 13 (2010), s. 2979-2984. ISSN 1439-4235. E-ISSN 1439-7641
Grant CEP: GA ČR(CZ) GA203/07/1257; GA MŠMT OC 177
Výzkumný záměr: CEZ:AV0Z40400503
Klíčová slova: cobalt * electrocatalysis * liquid/liquid interfaces
Kód oboru RIV: CG - Elektrochemie
Impakt faktor: 3.339, rok: 2010

Oxygen reduction catalyzed by cobalt(II) (2,3,7,8,12,13,17,18-octaethylporphyrin) [Co(OEP)] at soft interfaces is studied by voltammetry and biphasic reactions. When Co(OEP) is present in a solution of 1,2-dichloroethane in contact. With an aqueous acidic solution, oxygen is reduced if the interface is positively polarized (water phase versus organic phase). This reduction reaction is facilitated when an additional electron donor, here ferrocene, is present in excess in the organic phase.
Trvalý link: http://hdl.handle.net/11104/0189302