Počet záznamů: 1
Reintroducing Azidodifluoromethane: Synthesis, Stability and [3+2] Cycloadditions
- 1.0495299 - ÚOCHB 2019 RIV DE eng J - Článek v odborném periodiku
Voltrová, Svatava - Putovný, Igor - Matoušek, V. - Klepetářová, Blanka - Beier, Petr
Reintroducing Azidodifluoromethane: Synthesis, Stability and [3+2] Cycloadditions.
European Journal of Organic Chemistry. Roč. 2018, č. 37 (2018), s. 5087-5090. ISSN 1434-193X. E-ISSN 1099-0690
Institucionální podpora: RVO:61388963
Klíčová slova: fluorinated compounds * azides * fluorine * difluoromethyl group * triazoles * synthetic methods
Obor OECD: Organic chemistry
Impakt faktor: 3.029, rok: 2018
Azidodifluoromethane was prepared in 65% yield from chlorodifluoromethane by a two-step synthesis using tributyl(difluoromethyl)ammonium chloride as an intermediate. The resulting azide was used in Huisgen azide-alkyne reactions and ketone [3+2] cycloadditions to access novel N-difluoromethyl-1,2,3-triazoles.
Trvalý link: http://hdl.handle.net/11104/0288883
Počet záznamů: 1