The Valence-localized Decacyanodiruthenium(III,II) Analogue of the Creutz-Taube Ion. Completing the Full d.sup.5./sup./d.sup.6./sup. triad [(NC).sub.5./sub.M(ć-pz)M(CN).sub.5./sub.].sup.5-./sup., M=Fe, Ru, Os; pz=pyrazine

Name: The Valence-localized Decacyanodiruthenium(III,II) Analogue of the Creutz-Taube Ion. Completing the Full d.sup.5./sup./d.sup.6./sup. triad [(NC).sub.5./sub.M(ć-pz)M(CN).sub.5./sub.].sup.5-./sup., M=Fe, Ru, Os; pz=pyrazine
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Scheiring, T.; Kaim, W.; Olabe, J. A.; Parise, A. R.; Fiedler, Jan

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The Valence-localized Decacyanodiruthenium(III,II) Analogue of the Creutz-Taube Ion. Completing the Full d.sup.5./sup./d.sup.6./sup. triad [(NC).sub.5./sub.M(ć-pz)M(CN).sub.5./sub.].sup.5-./sup., M=Fe, Ru, Os; pz=pyrazine

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0181038 - UFCH-W 20000209 RIV CH eng J - Článek v odborném periodiku
Scheiring, T. - Kaim, W. - Olabe, J. A. - Parise, A. R. - Fiedler, Jan
The Valence-localized Decacyanodiruthenium(III,II) Analogue of the Creutz-Taube Ion. Completing the Full d⁵/d⁶ triad [(NC)₅M(ć-pz)M(CN)₅]^5-, M=Fe, Ru, Os; pz=pyrazine.
Inorganica chimica acta. 300-302, - (2000), s. 125-130. ISSN 0020-1693. E-ISSN 1873-3255
Grant CEP: GA MŠMT OC D15.10
Výzkumný záměr: CEZ:AV0Z4040901; CEZ:A54/98:Z4-040-9-ii
Kód oboru RIV: CG - Elektrochemie
Impakt faktor: 1.200, rok: 2000

The new ruthenium(II) complex ion [(NC)₅Ru(pz)Ru(CN)₅]^6- has been prepared and studied as the hexakis(tetraethylammonium) salt. The compound could be oxidized via two reversible one-electron steps with a mixed-valent pentaanionic intermediate.
Trvalý link: http://hdl.handle.net/11104/0077646

Počet záznamů: 1