Determination of Composition and Anomeric Ratio in Mixtures of Fluorinated Ologosaccharides.

0521796 - ÚCHP 2020 CZ eng C - Konferenční příspěvek (zahraniční konf.)
Červenková Šťastná, Lucie - Kurfiřt, Martin - Hamala, Vojtěch - Karban, Jindřich
Determination of Composition and Anomeric Ratio in Mixtures of Fluorinated Ologosaccharides.
Book of Abstracts. Prague: Institute of Chemical Process Fundamentals of the CAS, v. v. i., 2019, s. 63, č. článku P17. ISBN 978-80-86186-97-9.
[Magnetic Moments in Central Europe 2019. Prague (CZ), 27.02.2019-03.03.2019]
Grant CEP: GA MŠMT(CZ) LM2015037
Institucionální podpora: RVO:67985858
Klíčová slova: deoxofluorinated oligosaccharides * glycosylation * 2D NMR techniques
Obor OECD: Organic chemistry

Plenthora of glycosylation reactions was performed and sophisticated NMR approach for characteriza-tion of the coressponding products was aplied. ID 19F and *H NMR were utilized for accurate derermina-tion of anomeric ratios and 2D NMR techniques as HSQC, HMBC and COSY were used to assign the signals of individual anomers. In some cases, spectrum simulation was necessary to obtain the desired parameters.
Trvalý link: http://hdl.handle.net/11104/0306362