High-pressure Phase Equilibrium in the {Carbon Dioxide (1) + 1-Chloropropane (2)} Binary System.

0472571 - ÚCHP 2017 RIV GB eng J - Článek v odborném periodiku
Chorazewski, M. - Aim, Karel - Wichterle, Ivan - Jacquemin, J. - Polishuk, I.
High-pressure Phase Equilibrium in the {Carbon Dioxide (1) + 1-Chloropropane (2)} Binary System.
Journal of Chemical Thermodynamics. Roč. 91, č. 12 (2015), s. 165-171. ISSN 0021-9614. E-ISSN 1096-3626
Grant CEP: GA AV ČR IAA400720710
Grant ostatní: BEMUSAC(XE) 72074-2002-04019
Institucionální podpora: RVO:67985858
Klíčová slova: vapour-liquid equilibrium * carbon dioxide * predictive modeling
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 2.196, rok: 2015

The current study reports original vapour-liquid equilibrium (VLE) for the system {CO2 (1) + 1-chloropropane (2)}. The measurements have been performed over the entire pressure-composition range for the T = (303.15, 313.15 and 328.15) K isotherms. The values obtained have been used for comparison of four predictive approaches, namely the equation of state (EoS) of Peng and Robinson (PR), the Soave modification of Benedict–Webb–Rubin (SBWR) EoS, the Critical Point-based Revised Perturbed-Chain Association Fluid Theory (CP-PC-SAFT) EoS, and the Conductor-like Screening Model for Real Solvents (COSMO-RS).
Trvalý link: http://hdl.handle.net/11104/0269841