0584976 - FZÚ 2025 RIV NL eng J - Článek v odborném periodiku
Ghasemi, L. - Abedi, A. - Abbasi, A. - Kučeráková, Monika - Dušek, Michal - Behzad, M.
Subtle structural variations in new mixed-ligand Cu(II) complexes with NN'O type unsymmetrical Schiff bases: Molecular docking against SARS-Cov-2 and its Omicron variant main proteases.
Inorganic Chemistry Communications. Roč. 159, Jan (2024), č. článku 111795. ISSN 1387-7003. E-ISSN 1879-0259
Grant CEP: GA MŠMT LM2023051
Institucionální podpora: RVO:68378271
Klíčová slova: Covid-19 * mixed-ligand * molecular docking * 6LU7-7TLL * Schiff base
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 4.4, rok: 2023

A variety of new mixed-ligand Schiff-base complexes with general formula [Cu(SBn)(py)]ClO4 (n = 1–5) and [Cu(SBn)(BTZ)]ClO4 (n = 1a–5a) were synthesized and characterized. In these complexes, the NN’O-type unsymmetrical Schiff-base ligands (SBn) were formed from the equimolar condensation of 1,2-ethylenediamine with salicylaldehyde (1, 1a), 3-methoxysalicylaldehyde (2, 2a), 3,5-dibromosalicylaldehyde (3, 3a), 3-methoxy-5-bromosalicylaldehyde (4, 4a) and 6-methoxysalicylaldehyde (5, 5a). The complexes were characterized by FT-IR and UV–Vis spectroscopy and elemental analysis. The crystal structures of the complexes 3, 2a, 3a, 4a and 5a were also obtained by single-crystal X-ray diffraction (SCXRD).
Trvalý link: https://hdl.handle.net/11104/0352762