0563647 - ÚFCH JH 2023 RIV CH eng J - Článek v odborném periodiku
Abbas, Ghulam - Zafar, Zahid Ali - Farjana, Jaishmin Sonia - Knížek, Karel - Houdková, Jana - Jiříček, Petr - Kalbáč, Martin - Červenka, Jiří - Frank, Otakar
The Effects of Ultrasound Treatment of Graphite on the Reversibility of the (De)Intercalation of an Anion from Aqueous Electrolyte Solution.
Nanomaterials. Roč. 12, č. 22 (2022), č. článku 3932. ISSN 2079-4991. E-ISSN 2079-4991
Grant CEP: GA ČR GA19-23986S; GA MŠMT EF16_026/0008382; GA MŠMT(CZ) EF16_019/0000760
Grant ostatní: Ministerstvo školství, mládeže a tělovýchovy - GA MŠk(CZ) CZ.02.1.01/0.0/0.0/16_026/0008382; OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Výzkumná infrastruktura: CzechNanoLab - 90110
Institucionální podpora: RVO:61388955 ; RVO:68378271
Klíčová slova: ultrasonication * graphite * intercalation
Obor OECD: Physical chemistry; Electrochemistry (dry cells, batteries, fuel cells, corrosion metals, electrolysis) (FZU-D)
Impakt faktor: 5.3, rok: 2022 ; AIS: 0.712, rok: 2022
Způsob publikování: Open access
DOI: https://doi.org/10.3390/nano12223932

Low cycling stability is one of the most crucial issues in rechargeable batteries. Herein, we study the effects of a simple ultrasound treatment of graphite for the reversible (de)intercalation of a ClO4− anion from a 2.4 M Al(ClO4)3 aqueous solution. We demonstrate that the ultrasound-treated graphite offers the improved reversibility of the ClO4− anion (de)intercalation compared with the untreated samples. The ex situ and in situ Raman spectroelectrochemistry and X-ray diffraction analysis of the ultrasound-treated materials shows no change in the interlayer spacing, a mild increase in the stacking order, and a large increase in the amount of defects in the lattice accompanied by a decrease in the lateral crystallite size. The smaller flakes of the ultrasonicated natural graphite facilitate the improved reversibility of the ClO4− anion electrochemical (de)intercalation and a more stable electrochemical performance with a cycle life of over 300 cycles.
Trvalý link: https://hdl.handle.net/11104/0335550