The development of a fully integrated 3D printed electrochemical platform and its application to investigate the chemical reaction between carbon dioxide and hydrazine

0532030 - ÚFCH JH 2021 RIV GB eng J - Článek v odborném periodiku
Escobar, J. G. - Vaněčková, Eva - Nováková Lachmanová, Štěpánka - Vivaldi, F. - Heyda, J. - Kubišta, Jiří - Shestivska, Violetta - Španěl, Patrik - Schwarzová-Pecková, K. - Rathouský, Jiří - Sebechlebská, Táňa - Kolivoška, Viliam
The development of a fully integrated 3D printed electrochemical platform and its application to investigate the chemical reaction between carbon dioxide and hydrazine.
Electrochimica acta. Roč. 360, NOV 2020 (2020), č. článku 136984. ISSN 0013-4686. E-ISSN 1873-3859
Grant CEP: GA ČR(CZ) GA19-12109S; GA ČR(CZ) GA18-09848S; GA MŠMT(CZ) LM2018124
Institucionální podpora: RVO:61388955
Klíčová slova: 3D printing * Carbon dioxide * Electrochemical measurements * Hydrazine * Numerical simulations
Obor OECD: Physical chemistry
Impakt faktor: 6.901, rok: 2020
Způsob publikování: Omezený přístup

The combination of computer assisted design and 3D printing has recently enabled fast and inexpensive manufacture of customized ‘reactionware’ for broad range of electrochemical applications. In this work bi-material fused deposition modeling 3D printing is utilized to construct an integrated platform based on a polyamide electrochemical cell and electrodes manufactured from a polylactic acid-carbon nanotube conductive composite. The cell contains separated compartments for the reference and counter electrode and enables reactants to be introduced and inspected under oxygen-free conditions. The developed platform was employed in a study investigating the electrochemical oxidation of aqueous hydrazine coupled to its bulk reaction with carbon dioxide. The analysis of cyclic voltammograms obtained in reaction mixtures with systematically varied composition confirmed that the reaction between hydrazine and carbon dioxide follows 1/1 stoichiometry and the corresponding equilibrium constant amounts to (2.8 ± 0.6) × 103. Experimental characteristics were verified by results of numerical simulations based on the finite-element-method.
Trvalý link: http://hdl.handle.net/11104/0310632