Počet záznamů: 1
Origin of the colossal permittivity of (Nb plus In) co-doped rutile ceramics by wide-range dielectric spectroscopy
- 1.0498094 - FZÚ 2019 RIV GB eng J - Článek v odborném periodiku
Petzelt, Jan - Nuzhnyy, Dmitry - Bovtun, Viktor - Crandles, D.A.
Origin of the colossal permittivity of (Nb plus In) co-doped rutile ceramics by wide-range dielectric spectroscopy.
Phase Transitions. Roč. 91, č. 9-10 (2018), s. 932-941. ISSN 0141-1594. E-ISSN 1029-0338
Grant CEP: GA ČR GA18-09265S; GA MŠMT EF16_019/0000760
Grant ostatní: OP VVV - SOLID21(XE) CZ.02.1.01/0.0/0.0/16_019/0000760
Institucionální podpora: RVO:68378271
Klíčová slova: dielectric spectroscopy * co-doped rutile ceramics * effective medium approximation * surface and internal barrier-layer capacitor effects
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Impakt faktor: 1.026, rok: 2018
Searching for giant dipolar defects, suggested as the explanation of the colossal permittivity (CP) in (Nb + In) co-doped rutile, we have recently published temperature-dependent dielectric spectra from sub-Hz to THz range (including 4-point DC conductivity) of several (Nb + In) co-doped rutile ceramics. Using the model of two leaky capacitor in series below ∼1 MHz, we estimated the depletion layer thickness and conductivity. The spectra below ∼10 GHz were fitted with two Cole–Cole relaxations obeying the Arrhenius law, assigned to the effect of depletion layers and grain boundaries. In this paper, using effective medium models, we have for the first time modelled the spectra as a composite of semiconducting grains and substantially less-conducting grain boundaries and near-electrode depletion layers. The CP effect has been fully explained by the combination of surface and internal barrier-layer capacitor effects, without any measurable contribution from the dipolar defects.
Trvalý link: http://hdl.handle.net/11104/0290513
Počet záznamů: 1