Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.

0482227 - ÚCHP 2018 MY eng C - Konferenční příspěvek (zahraniční konf.)
Storch, Jan - Žádný, Jaroslav - Strašák, Tomáš - Hrbáč, J. - Fekete, Ladislav - Pokorný, Jan - Bulíř, Jiří - Vacek, J.
Potential-driven On/Off Switch Strategy for the Electrosynthesis of [7]Helicene-derived Polymers.
Souvenir Programme. -: -, 2017. ISBN N.
[POLYCHAR 2017 World Forum on Advanced Materials /25./. Kuala Lumpur (MY), 09.10.2017-13.10.2017]
Grant CEP: GA MPO FV10082
Institucionální podpora: RVO:67985858
Klíčová slova: helicene * anodic reaction * electropolymerization
Obor OECD: Organic chemistry; Physical chemistry (FZU-D)

3-([7]Helicen-9-yl)-thiophene hybrid monomer was electrooxidized in acetonitrile by cyclic voltammetry with anodic potential limits of +1.5 V or +2.5 V, resulting in a conductive and non-conductive polymer, respectively. The electrochemical findings were supplemented by microscopy investigations; UV-Vis, fluorescence and vibrational spectroscopies, ellipsometry measurements and computational chemistry. The electrodeposited polymers could be used for the further development of materials applicable in organic electronics and sensing technologies.
Trvalý link: http://hdl.handle.net/11104/0277609