Počet záznamů: 1  

Phase Behavior of Semiflexible-Flexible Diblock Copolymer Melt: Insight from Mesoscale Modeling.

  1. 1. 0472476 - UCHP-M 2017 RIV US eng J - Článek v odborném periodiku
    Beránek, P. - Posel, Zbyšek
    Phase Behavior of Semiflexible-Flexible Diblock Copolymer Melt: Insight from Mesoscale Modeling.
    Journal of Nanoscience and Nanotechnology. Roč. 16, č. 8 (2016), s. 7832-7835. ISSN 1533-4880
    Grant CEP: GA MŠk(CZ) LH12020
    Institucionální podpora: RVO:67985858
    Klíčová slova: conformational asymmetry * dissipative particle dynamics * mesoscale modeling
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 1.483, rok: 2016

    Phase behavior of semiflexible-flexible diblock copolymer melt with conformational asymmetry epsilon >= 1 is studied by means of mesoscale modeling. It is shown that phase behavior of melt with epsilon = 1 follows predictions from self-consistent field theory while symmetry of phase diagram is broken for melts with epsilon > 1. Moreover, increasing of epsilon leads to replacement of gyroid nanostructure by more stable cylindrical and lamellar nanostructures. Our results are in agreement with experimental observations.
    Trvalý link: http://hdl.handle.net/11104/0269777