Mo-II Cluster Complex-Based Coordination Polymer as an Efficient Heterogeneous Catalyst in the Suzuki–Miyaura Coupling Reaction

0462104 - ÚACH 2017 RIV DE eng J - Článek v odborném periodiku
Bůžek, Daniel - Hynek, Jan - Kučeráková, Monika - Kirakci, Kaplan - Demel, Jan - Lang, Kamil
Mo-II Cluster Complex-Based Coordination Polymer as an Efficient Heterogeneous Catalyst in the Suzuki–Miyaura Coupling Reaction.
European Journal of Inorganic Chemistry. Roč. 2016, č. 28 (2016), s. 4668-4673. ISSN 1434-1948. E-ISSN 1099-0682
Grant CEP: GA ČR GA13-05114S; GA ČR GA15-12653S
GRANT EU: European Commission(XE) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:61388980 ; RVO:68378271
Klíčová slova: C–C coupling * Heterogeneous catalysis * Molybdenum * Palladium * Polymers
Kód oboru RIV: CA - Anorganická chemie; CF - Fyzikální chemie a teoretická chemie (FZU-D)
Impakt faktor: 2.444, rok: 2016

The design and preparation of highly active heterogeneous palladium catalysts is attracting ever-increasing attention. In this paper, we report on the self-assembly of palladium centers and an octahedral molybdenum cluster complex bearing phosphine terminal ligands. This leads to a coordination polymer exhibiting high catalytic activity in the Suzuki–Miyaura cross-coupling reaction. The coordination polymer achieved a turnover number of 15800 in a reaction of deactivated aryl bromides with phenylboronic acid. Because metal clusters represent rare building blocks for the preparation of heterogeneous palladium catalysts, this work points to new structural motives that can be utilized to develop highly active heterogeneous catalysts.
Trvalý link: http://hdl.handle.net/11104/0263375