Počet záznamů: 1  

Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation

  1. 1. 0461488 - FZU-D 2017 RIV US eng J - Článek v odborném periodiku
    Kocić, N. - Liu, X. - Chen, S. - Decurtins, S. - Krejčí, Ondřej - Jelínek, Pavel - Repp, J. - Liu, S.
    Control of reactivity and regioselectivity for on-surface dehydrogenative aryl-aryl bond formation.
    Journal of the American Chemical Society. Roč. 138, č. 17 (2016), s. 5585-5593 ISSN 0002-7863
    Grant CEP: GA ČR(CZ) GC14-16963J
    Institucionální podpora: RVO:68378271
    Klíčová slova: on-surface reaction * AFM * DFT * metal-organic coordination
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 13.858, rok: 2016

    Here we exploit a combined STM/AFM technique to demonstrate the on-surface formation of complex molecular architectures built up from a heteroaromatic precursor, the tetracyclic pyrazino[2,3-f][4,7]phenanthroline (pap) molecule. Selective intermolecular aryl–aryl coupling via dehydrogenative C–H activation occurs on Au(111) upon thermal annealing under ultrahigh vacuum (UHV) conditions.
    Trvalý link: http://hdl.handle.net/11104/0261790