Počet záznamů: 1  

Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons

  1. 1. 0455656 - UACH-T 2016 RIV PL eng J - Článek v odborném periodiku
    Distler, P. - Kondé, J. - John, J. - Hájková, Zuzana - Švehla, Jaroslav - Grüner, Bohumír
    Characterization of solvents containing CyMe4-BTPhen in selected cyclohexanone-based diluents after irradiation by accelerated electrons.
    Nukleonika. Roč. 60, č. 4 (2015), s. 885-891. ISSN 0029-5922
    Grant CEP: GA MŠk(CZ) 7G13003
    GRANT EU: European Commission(XE) 323282 - SACSESS
    Institucionální podpora: RVO:61388980
    Klíčová slova: accelerated electrons * CyMe4-BTPhen * irradiation * radiation stability * solvent extraction
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 0.546, rok: 2015

    Radiation stability of CyMe4-BTPhen was examined in systems with three selected cyclohexanone--based diluents. Accelerated electrons were used as a source of ionizing radiation. The CyMe4-BTPhen radiation degradation identification and characterization of the degradation products were performed by high performance liquid chromatography (HPLC) and mass spectrometry (MS) analyses. Residual concentrations of tested ligand were determined. Moreover, extraction properties of the solvents irradiated at two different doses were compared with the extraction properties of non-irradiated solvents to estimate the influence of the presence of degradation products in the organic phase.
    Trvalý link: http://hdl.handle.net/11104/0256280