0439949 - ÚOCHB 2015 RIV CZ eng C - Konferenční příspěvek (zahraniční konf.)
Jaklová Dytrtová, Jana - Jakl, M. - Schröder, Detlef
Ferrocene Oxidation; a Hyphenation of Voltammetry with Electrospray Ionization Mass Spectrometry.
Sborník přednášek. XXXI. Moderní elektrochemické metody. Ústí nad Labem: BEST servis, 2011 - (Navrátil, T.; Barek, J.), s. 69-73. ISBN 978-80-254-9634-3.
[Moderní elektrochemické metody /31./. Jetřichovice (CZ), 23.05.2011-27.05.2011]
Grant CEP: GA ČR GA203/08/1487
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: ESI-MS * DPASV * CV * ferrocene * base electrolyte
Kód oboru RIV: CG - Elektrochemie

The coupling of ESI-MS with two-electrodes flowing cell was provided and tested on ferrocene system. The oxidation potential of ferrocene was 430 mV in Pt/Ag electrode system. The bis-coordinated ferrocene complex with base electrolyte (NaClO4) was found using DPASV provided in different accumulation potentials and its analogy was also observed as protonated cation in mass spectra. The impact of inserted accumulation potential on mass spectra was also studied; the inserted potential changes the natural pattern of ferrocene.
Trvalý link: http://hdl.handle.net/11104/0243314