0439356 - ÚCHP 2015 RIV JP eng C - Konferenční příspěvek (zahraniční konf.)
Huang, L.-W. - Jian, Y.-J. - Huang, Ch.-Y. - Chyou, Y.-P. - Svoboda, Karel
Application of Silica-supported Sorbents into Coal Derived Syngas Desulfurization Field for Clean Coal Technologies Development.
Proceedings of Abstracts from the ACEAT 2014. Osaka: -, 2014, s. 1-10. ISBN 978-986-90827-7-8.
[2014 The Annual Conference on Engineering and Technology. Osaka (JP), 15.11.2014-17.11.2014]
Grant CEP: GA ČR GC14-09692J
Institucionální podpora: RVO:67985858
Klíčová slova: syngas * breakthrough time * sulfur capacity
Kód oboru RIV: JE - Nejaderná energetika, spotřeba a využití energie

Silica-supported sorbents with Cu, Mn or Fe metal oxide have been synthesized by impregnation method. The physical properties of the sorbents were analyzed by XRD and chemical composition by ICP-AES. The experiments on sulfur capture used simulated syngas (1 vol. % H2S, 30 % CO, 10 % H2, 5 % CO2, N2 for balance) and fixed bed reactor with solid sorbents. The results have shown, that the iron based sorbent had the best sulfure-capture ability and capacity (8.17 g S/100 g of sorbent). With increasing CO2 concentration (5 – 20 %) the sulfure capturing ability decreased (from 8.17 to 5.8 g S/100 g of sorbent). After 5 cyclic tests the sulfur-capture ability of the iron –based sorbent decreased only very slightly. It seems the sorbent is promising for clean coal technologies related gas cleaning processes.
Trvalý link: http://hdl.handle.net/11104/0242642