0436182 - FZÚ 2015 RIV US eng J - Článek v odborném periodiku
Roussel, P. - Palatinus, Lukáš - Belva, F. - Daviero-Minaud, S. - Mentre, O. - Huve, M.
Sr₄Ru₆ClO₁₈, a new Ru⁴⁺/⁵⁺ oxy-chloride,solved by precession electron diffraction: electric and magnetic behavior.
Journal of Solid State Chemistry. Roč. 212, Apr (2014), s. 99-106. ISSN 0022-4596. E-ISSN 1095-726X
Institucionální podpora: RVO:68378271
Klíčová slova: ruthenium oxide * precession * electron crystallography * transport properties * mixed valence
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 2.133, rok: 2014 ; AIS: 0.55, rok: 2014
DOI: https://doi.org/10.1016/j.jssc.2014.01.012

The crystal structure of Sr4Ru6ClO18, a new Ru4+/5+ oxy-chloride,has been determined from Precession Electron Diffraction(PED) data acquired on an nanoocrystal in a transmissio nelectron microscope using the technique of electron diffraction tomography. This approach is described in details following a pedagogic route and a systematic comparison is made of this rather new method with other experimental methods of electron diffraction, and with the standard singlecrystal X-ray diffraction technique. Both transport and magnetic measurements, showed a transition at low temperature that may be correlated to Ru4+/5+ charge ordering.
Trvalý link: http://hdl.handle.net/11104/0239977