0435895 - ÚFCH JH 2016 RIV GB eng J - Článek v odborném periodiku
Krýsová, Hana - Vlčková Živcová, Zuzana - Bartoň, Jan - Petrák, Václav - Nesladek, M. - Cígler, Petr - Kavan, Ladislav
Visible-light sensitization of boron-doped nanocrystalline diamond through non-covalent surface modification.
Physical Chemistry Chemical Physics. Roč. 17, č. 2 (2015), s. 1165-1172. ISSN 1463-9076. E-ISSN 1463-9084
Grant CEP: GA ČR GA13-31783S
Institucionální podpora: RVO:61388955 ; RVO:61388963 ; RVO:68378271
Klíčová slova: nanocrystallines * visible-light sensitization * boron-doped diamond
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 4.449, rok: 2015 ; AIS: 1.158, rok: 2015
DOI: https://doi.org/10.1039/C4CP04148H

A novel simple and versatile synthetic strategy is developed for the surface modification of boron-doped diamond. In a two-step procedure, polyethyleneimine is adsorbed on the hydrogenated diamond surface and subsequently modified with a model light-harvesting donor-π-bridge-acceptor molecule (coded P1). The sensitized diamond exhibits stable cathodic photocurrents under visible-light illumination in aqueous electrolyte solution with dimethylviologen serving as an electron mediator. In spite of the simplicity of the surface sensitization protocol, the photoelectrochemical performance is similar to or better than that of other sensitized diamond electrodes which were reported in previous studies (2008–2014).
Trvalý link: http://hdl.handle.net/11104/0239724