0435000 - ÚFCH JH 2015 RIV DE eng J - Článek v odborném periodiku
Wheatley, P. S. - Eliášová, Pavla - Greer, H. F. - Zhou, W. - Seymour, V. R. - Dawson, D. M. - Ashbrook, S. E. - Pinar, A. B. - McCusker, L.B. - Opanasenko, Maksym - Čejka, Jiří - Morris, R. E.
Zeolites with Continuously Tuneable Porosity.
Angewandte Chemie - International Edition. Roč. 53, č. 48 (2014), s. 13210-13214. ISSN 1433-7851. E-ISSN 1521-3773
Grant CEP: GA ČR GBP106/12/G015
Institucionální podpora: RVO:61388955
Klíčová slova: ADOR * germanosilicates * porosity * zeolites
Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
Impakt faktor: 11.261, rok: 2014 ; AIS: 3.39, rok: 2014
DOI: https://doi.org/10.1002/anie.201407676

Zeolites are important materials whose utility in industry depends on the nature of their porous structure. Control over microporosity is therefore a vitally important target. Unfortunately, traditional methods for controlling porosity, in particular the use of organic structure-directing agents, are relatively coarse and provide almost no opportunity to tune the porosity as required. Here we show how zeolites with a continuously tuneable surface area and micropore volume over a wide range can be prepared. This means that a particular surface area or micropore volume can be precisely tuned. The range of porosity we can target covers the whole range of useful zeolite porosity: from small pores consisting of 8-rings all the way to extra-large pores consisting of 14-rings.
Trvalý link: http://hdl.handle.net/11104/0238967