A new copper(I) coordination polymer with N.sub.2./sub.-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies

0434249 - FZÚ 2015 RIV US eng J - Článek v odborném periodiku
Khalaji, A.D. - Rohlíček, Jan - Machek, Pavel - Das, D.
A new copper(I) coordination polymer with N₂-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies.
Journal of Cluster Science. Roč. 25, č. 5 (2014), s. 1425-1434. ISSN 1040-7278. E-ISSN 1572-8862
Grant ostatní: AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Institucionální podpora: RVO:68378271
Klíčová slova: copper(I) complex * schiff base * spectroscopy * thermal study * nanoparticle * SEM * XRD
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.302, rok: 2014

A new copper(I) coordination polymer, [Cu((3,4-MeO-ba)2bn)I]n (1), using a bridging Schiff base ligand, N,N0-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine, (3,4-MeO-ba)2bn, containing a flexible spacer (=N–CH2–CH2–CH2–CH2–N=) has been synthesized and characterized by elemental analyses (CHN) and FTIR spectroscopy, thermal analysis and powder X-ray structure analysis. In 1, Cu(I) ions are bridged by Schiff base ligands and iodine atoms forming 1D-chain. The thermal stability of 1 was studied by thermal gravimetric and differential thermal analyses. 1 is used to prepare CuO nanoparticles via solid state thermal decomposition in air and nanoparticles thus formed are characterized by scanning electron microscopy, transmission electron microscopy and powder X-ray diffraction techniques.
Trvalý link: http://hdl.handle.net/11104/0238342