Počet záznamů: 1  

A new copper(I) coordination polymer with N.sub.2./sub.-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies

  1. 1. 0434249 - FZU-D 2015 RIV US eng J - Článek v odborném periodiku
    Khalaji, A.D. - Rohlíček, Jan - Machek, Pavel - Das, D.
    A new copper(I) coordination polymer with N2-donor schiff base and Its use as precursor for CuO nanoparticle: Spectroscopic, thermal and structural studies.
    Journal of Cluster Science. Roč. 25, č. 5 (2014), s. 1425-1434 ISSN 1040-7278
    Grant ostatní:AV ČR(CZ) AP0701
    Program:Akademická prémie - Praemium Academiae
    Institucionální podpora: RVO:68378271
    Klíčová slova: copper(I) complex * schiff base * spectroscopy * thermal study * nanoparticle * SEM * XRD
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 1.302, rok: 2014

    A new copper(I) coordination polymer, [Cu((3,4-MeO-ba)2bn)I]n (1), using a bridging Schiff base ligand, N,N0-bis(3,4-dimethoxybenzylidene)butane-1,4-diamine, (3,4-MeO-ba)2bn, containing a flexible spacer (=N–CH2–CH2–CH2–CH2–N=) has been synthesized and characterized by elemental analyses (CHN) and FTIR spectroscopy, thermal analysis and powder X-ray structure analysis. In 1, Cu(I) ions are bridged by Schiff base ligands and iodine atoms forming 1D-chain. The thermal stability of 1 was studied by thermal gravimetric and differential thermal analyses. 1 is used to prepare CuO nanoparticles via solid state thermal decomposition in air and nanoparticles thus formed are characterized by scanning electron microscopy, transmission electron microscopy and powder X-ray diffraction techniques.
    Trvalý link: http://hdl.handle.net/11104/0238342