Počet záznamů: 1  

Cu–Ni nanoalloy phase diagram – Prediction and experiment

  1. 1. 0420992 - UFM-A 2015 RIV GB eng J - Článek v odborném periodiku
    Sopoušek, J. - Vřešťál, J. - Pinkas, J. - Brož, P. - Buršík, Jiří - Stýskalík, A. - Škoda, D. - Zobač, O. - Lee, J.
    Cu–Ni nanoalloy phase diagram – Prediction and experiment.
    Calphad - Computer Coupling of Phase Diagrams and Thermochemistry. Roč. 45, June (2014), s. 33-39 ISSN 0364-5916
    Institucionální podpora: RVO:68081723
    Klíčová slova: nanoalloy * phase diagram * thermodynamic modeling
    Kód oboru RIV: BJ - Termodynamika
    Impakt faktor: 1.370, rok: 2014

    The Cu–Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu–Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The nanoparticle size, chemical composition, and Cu–Ni nanoparticles melting temperature depression were obtained. The experimental temperatures of melting of nanoparticles were in good agreement with the theoretical CALPHAD predictions considering surface energy.
    Trvalý link: http://hdl.handle.net/11104/0228203