0420983 - ÚCHP 2014 RIV GB eng J - Článek v odborném periodiku
Hudeček, O. - Cuřínová, Petra - Budka, J. - Lhoták, P.
Regioselective Upper Rim Substitution of Calix[4]arenes.
Tetrahedron. Roč. 67, č. 29 (2011), s. 5213-5218. ISSN 0040-4020. E-ISSN 1464-5416
Grant CEP: GA ČR GA203/09/0691; GA AV ČR IAAX08240901
Institucionální podpora: RVO:67985858
Klíčová slova: calixarene * electrophilic substitution * anion recognition
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 3.025, rok: 2011 ; AIS: 0.727, rok: 2011
DOI: https://doi.org/10.1016/j.tet.2011.05.049

The electrophilic substitution of 25,27-dipropoxy-26,28-dinosyloxycalix[4]arene leads exclusively to the para-substitution of the alkylated phenol rings, while in the next step, the protecting nosyl group can be easily removed using a basic hydrolysis. The overall process yields dialkoxycalix[4]arenes with the substitution on the alkylated rings—the substitution pattern, which is complementary to the common dialkoxycalix[4]arenes with substituted nonalkylated phenolic units. The usefulness of this protection/deprotection procedure was documented by the synthesis of novel type of calixarene dipropoxy derivatives, and by the preparation of a novel anion receptor based on this substitution pattern.
Trvalý link: http://hdl.handle.net/11104/0227460