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(2S,7S )-10-Ethyl-1,8,10,12-tetraazatetracyclo-[8.3.1.1 .sup.8,12./sup..0.sup.2,7./sup.]pentadecan-10-ium iodide
- 1.0384349 - FZÚ 2013 RIV DK eng J - Článek v odborném periodiku
Rivera, A. - Osorio, H.J. - Sadat-Bernal, J. - Eigner, Václav - Dušek, Michal
(2S,7S )-10-Ethyl-1,8,10,12-tetraazatetracyclo-[8.3.1.1 8,12.02,7]pentadecan-10-ium iodide.
Acta Crystallographica Section E-Structure Reports Online. Roč. 68, Part 10 (2012), "o3041"-"sup7". ISSN 1600-5368. E-ISSN 2056-9890
Grant ostatní: AV ČR(CZ) AP0701
Program: Akademická prémie - Praemium Academiae
Výzkumný záměr: CEZ:AV0Z10100521
Klíčová slova: organic structure * Jana2006
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 0.347, rok: 2011 ; AIS: 0.035, rok: 2011
DOI: https://doi.org/10.1107/S1600536812040159
The title chiral quaternary ammonium salt, C13H25N4+.I-, was synthesized through the Menschutkin reaction between the cage aminal (2S,7S)-1,8,10,12-tetraazatetracyclo- [8.3.1.1 8,12 .02,7]pentadecan-10-ium iodide . The quaternization occurred regioselectively on the nitrogen with major sp3 character. The crystal structure consists of anions and cations separated by normal distances. Ions are not linked through C-H...I hydrogen bonds.
Trvalý link: http://hdl.handle.net/11104/0214035
Počet záznamů: 1