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TiO2 Powders Synthesized by Pressurized Fluid Extraction and Supercritical Drying: Effect of Water and Methanol on Structural Properties and Purity

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    0380909 - ÚCHP 2013 RIV GB eng J - Článek v odborném periodiku
    Matějová, Lenka - Matěj, Z. - Fajgar, Radek - Cajthaml, Tomáš - Šolcová, Olga
    TiO2 Powders Synthesized by Pressurized Fluid Extraction and Supercritical Drying: Effect of Water and Methanol on Structural Properties and Purity.
    Materials Research Bulletin. Roč. 47, č. 11 (2012), s. 3573-3579. ISSN 0025-5408. E-ISSN 1873-4227
    Grant CEP: GA ČR GP104/09/P290
    Institucionální podpora: RVO:67985858 ; RVO:61388971
    Klíčová slova: oxides * sol-gel chemistry * X-ray diffraction
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 1.913, rok: 2012

    Pressurized water extraction followed by sub/supercritical methanol drying was used for synthesis of TiO2 from gels prepared by sol–gel technique using Triton X-114 like template. It was proved that pressurized water causes titania crystallization. Subsequent sub/supercritical methanol drying is responsible for total elimination of the rest of organic phase originating from the template. The impact of temperature and pressure modifications on titania purity was more essential for pressurized water extraction. The specific surface area significantly increases with removal of the residual organic phase. Anatase was a dominant crystalline phase. The fraction of minor brookite was in the range 20–30 wt.%. In situ XRD showed stability of titania crystallites size up to 300 8C and the presence of brookite crystallites even up to 600 8C. The correlation between Raman FWHM and XRD crystallite size was not influenced by the presence of organic phase and was more sensitive for anatase Eg band 647 cm-1.
    Trvalý link: http://hdl.handle.net/11104/0215380

     
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