The MRCI studies of low-lying electronic states of Al.sub.3./sub. and Al.sup.-./sup.3

0361538 - ÚMCH 2012 RIV NL eng J - Článek v odborném periodiku
Czernek, Jiří - Živný, Oldřich
The MRCI studies of low-lying electronic states of Al₃ and Al^-3.
Chemical Physics Letters. Roč. 512, 1-3 (2011), s. 40-43. ISSN 0009-2614. E-ISSN 1873-4448
Grant CEP: GA ČR GAP205/11/2070
Výzkumný záměr: CEZ:AV0Z40500505; CEZ:AV0Z20430508
Klíčová slova: Al3 * excitations * MRCI
Kód oboru RIV: BL - Fyzika plazmatu a výboje v plynech
Impakt faktor: 2.337, rok: 2011

The photodetachment transitions from two electronic states of Al3- to four states of Al3 have been studied by the MRCI calculations in an excellent agreement with the results of recent measurements on these systems, and the assignment of the transitions has been confirmed. Also the higher excited states have been characterized, and for 2 2B2, 4A2", 2A2, and terms of Al3 substantial differences between their MRCI and single-reference descriptions have been found.
Trvalý link: http://hdl.handle.net/11104/0006517